摘要
从18电子规则发展出来的过渡金属簇合物的有关结构规则和计算方法在处理簇骨架内含填隙原子的簇合物时,需要附加一个经验法则才能取得较好效果。文中从实验数据出发论证了这个经验法则的合理性,揭示了其物理意义。并讨论了它和理论规则之间的联系。
When the transition metal cluster compounds containing the metal atoms which are located in the inner of cluster body are explained, an experimental rule is to be added to some structural rules which evolve from 18-electrons rule. In this paper, the reasonableness of the experimental rule is discussed on the basis of experiment data and the relationship between the experimental rule and theoretical rules is given.
出处
《大庆石油学院学报》
CAS
北大核心
1990年第4期70-73,共4页
Journal of Daqing Petroleum Institute
关键词
过渡金属
簇合物
结构
cluster compounds
structure
18-electrons rule
