摘要
The title compound 1,5-diphenyl-3-phenacylthio-1H-1,2,4-triazole 2 （C22H17- N3OS, Mr = 371.45） was prepared by the reaction of 1-benzoyl-3-phenyl-aminothiourea 1 with 2-bromoacetophenone. The crystal is of triclinic, space group P^1-, a = 8.906（3）, b = 9.853（3）, c = 11.226（4）A, α= 100.562（5）, β= 101.285（5）, γ. = 105.096（6）^c, Z = 2, V = 903.7（5） ]A^3, Dc= 1.365 g/cm^3,μ（MoKa） = 0.196 mm^-1, F（000） = 388, the final R = 0.0506 and wR = 0.0985 for 2532 observed reflections （I〉 2σ（I））. Its formation mechanism was proposed.
The title compound 1,5-diphenyl-3-phenacylthio-1H-1,2,4-triazole 2 （C22H17- N3OS, Mr = 371.45） was prepared by the reaction of 1-benzoyl-3-phenyl-aminothiourea 1 with 2-bromoacetophenone. The crystal is of triclinic, space group P^1-, a = 8.906（3）, b = 9.853（3）, c = 11.226（4）A, α= 100.562（5）, β= 101.285（5）, γ. = 105.096（6）^c, Z = 2, V = 903.7（5） ]A^3, Dc= 1.365 g/cm^3,μ（MoKa） = 0.196 mm^-1, F（000） = 388, the final R = 0.0506 and wR = 0.0985 for 2532 observed reflections （I〉 2σ（I））. Its formation mechanism was proposed.
基金
The project was supported by the Key Laboratory of Organic Synthesis of Jiangsu Province (JSK016)
