期刊文献+

2-氯乙烯基二氯化硼的合成

Synthesis of 2-chlorovinylboron Dichloride
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摘要 2-Chlorovinylboron dichloride was synthesized with boron chloride and acetylene in granular activecarbon.Inthe solution of mercuric chloride the carbon was dryedlow70℃.It was foundthat bath with car-bon dioxide and acetone is needless if the end gas enteredin a bag.The synthesisinstrument was added a dis-tilled system. 2-Chlorovinylboron dichloride was synthesized with boron chloride and acetylene in granular active carbon. In the solution of mercuric chloride the carbon was dryed low 70℃. It was found that' bath with carbon dioxide and acetone is needless if the end gas entered in a bag. The synthesis instrument was added a distilled system.
出处 《四川大学学报(自然科学版)》 CAS CSCD 北大核心 2006年第4期939-940,共2页 Journal of Sichuan University(Natural Science Edition)
基金 中国核动研究设计院核燃料及材料国家重点实验室基金(51481030103SC0101)
关键词 三氯化硼 合成装置 乙烯基 激光分离 分解反应 实验条件 蒸馏系统 同位数 催化剂 活性炭 2-chlorovinylboron dichloride oxygen less and waterless system synthesis instrument with a distilled system
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参考文献4

  • 1Herrick R A. Brandywine H D, Chemical Compounds and Processes: Uited States Patent, 2,402,589[P]. 1946-6-25.
  • 2Gipstein E, Kippur P R, et al, Preparation of (2-Chlorovinyl) ethylchloroborane and Bis(2-chlorovinyl) ethylborane[J], J Org Chem, 1961,26(4) :943.
  • 3Gipstein E, Kippur P R, Mark A H. Organoboron Compounds. I, The Preparation of 2-Chlorovinyl- and 2-Clorovinylethylboranes by Vinylation, Disproportionnation and Exchange Reactions[J], J Org Chem, 1961,26(5) :2947.
  • 4Jensen, et al. Method of Separating Boron Isotopes: Uited States Patent, 4,447,303[P]. 1984-5-8.

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