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乙醛酸酯-烯不对称催化反应的研究进展 被引量：2

Research developments in asymmetric catalysis of glyoxylate-ene reaction
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摘要 催化乙醛酸酯-烯反应(glyoxylate-ene reaction)合成具有光学活性的α-羟基酯需要运用手性催化剂。本文主要介绍了该类手性催化剂的研究进展。 The asymmetric catalysis of glyoxylate-ene reaction is one of the most important methods for preparation of optical-purity α-hydroxy esters,which is a building block in organic synthesis. This review mainly focused on the developments of the catalysts for the asymmetric glyoxylate-ene reaction.
作者 谢翼 沈振陆 莫卫民 胡宝祥 孙楠
机构地区 浙江工业大学化学工程与材料学院
出处 《化学试剂》 CAS CSCD 北大核心 2006年第8期465-470,共6页 Chemical Reagents
基金 浙江省自然科学基金项目(Y404058)资助
关键词 乙醛酸酯-烯反应 不对称合成 对映选择性 glyoxylate-ene reaction asymmetric synthesis enan- tioselective
分类号 O625.63 [理学—有机化学]
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参考文献33

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同被引文献9

  • 1Scheffler U,Mahrwald R.Histidine-catalyzed asymmetric aldol addition of enolizable aldehydes:Insights into its mechanism[J].Journal of Organic Chemistry,2012,77:2310-2330.
  • 2Lam Y H,Houk K N,Scheffler U,et al.Stereoselectivities of histidine-catalyzed asymmetric aldol additions and contrasts with proline catalysis:A auantum mechanical analysis[J].Journal of the American Chemical Society,2012,134:6286-6295.
  • 3Qian Y B,Zheng X,Wang X,et al.An efficient Ionic liquid additive for proline catalyzed direct asymmetric aldol reaetions between cyelic ketones and aromatic aldehydes[J].Chemistry Letters,2009,38:576-577.
  • 4Zhou L,Wang L.Chiral ionic liquid containing L-proline unit as a highly effieient and recyelable asymmetric organocatalyst for aldol reaction[J].Chemistry Letters,2007,36:628-629.
  • 5Siyutkin D E,Kucherenko A S,Struchkova M I,et al.A novel(S)-proline-modified task-specific chiral ionic liquid an amphiphilic recoverable catalyst for direct asymmetric Aldol reactions in water[J].Tetrahedron Letters,2008,49:1212-1216.
  • 6李楠,刘伟军,龚流柱.手性有机小分子催化最新进展[J].化学进展,2010,22(7):1362-1379. 被引量：13
  • 7安众福,陈润锋,史慧芳,马琮,石乃恩,黄维.联萘酚衍生物的光电功能及其应用[J].化学进展,2010,22(10):1973-1982. 被引量：3
  • 8吕俊敏,范素兵,张建利.[Bmim]OH催化酯交换合成碳酸二丙酯[J].青岛科技大学学报（自然科学版）,2012,33(6):556-559. 被引量：2
  • 9杨丽,徐括喜,王晨娟,王超杰.基于2,2'-联萘酚衍生物的荧光化学传感器对手性异构体选择性识别研究进展[J].有机化学,2013,33(12):2496-2503. 被引量：9

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化学试剂
2006年 第8期

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