摘要
本文综述了近年来非均相金属卟啉催化剂的最新研究成果,对不同类型载体的结构特点、负载方法、及催化活性进行了详细阐述。负载后的金属卟啉配合物不仅避免了二聚,提高了稳定性和活性,而且表现出较高的形状和尺寸选择性。
New research results on heterogeneous metalloporphyrin catalysts in recent years have been reviewed in this paper. The structure features of different supporters and immobilizing methods and the activities of heterogeneous catalysts have been described in detail. Immobilized metalloporphyrins avoid to form dimmerization and have high stability, activity and shape and size selectivity.
出处
《化学研究与应用》
CAS
CSCD
北大核心
2006年第8期889-895,共7页
Chemical Research and Application
基金
北京市自然科学基金资助项目(2032002)
关键词
金属卟啉
模拟酶
非均相催化剂
metalloporphyrins
mimic enzyme
heterogeneous catalysts
