部分气体双原子分子的完全振动能谱和离解能的精确研究

Studies on the full vibrational energy spectra and molecular dissociation energies for some electronic states of gas diatomic molecules

鉴于气体双原子分子H2、O2、N2和CO的高振动激发态能级和离解行为在实际研究中的重要性,本文应用代数方法(AM)和代数能量方法(AEM),以部分气体双原子分子有限的实验能级[Ev]为基础,获得了H2-X1∑+g、O2-A3∑+u、O2-c1∑-u、N2-X1∑+g和CO-X1∑+共5个电子态的完全振动能谱{Ev}及其分子的离解能,为研究部分离解气体的物理和化学性质提供了重要的高振动激发态能级和可靠的离解能数据.

Since the High-Lying Vibrational excited levels and dissociate behavior of gas diatomie molecules： H2, O2, N2 and CO are very important in actual studies and applications, using the algebra method （AM） and the algebra energy method （AEM） to obtained full vibrational energy spectra {Ev} and molecular dissociation energies are base on limited experiment energy level {Ev} in this paper. The study result has provided the important high vibrational excited state energy level and the reliable dissociation energy data for the research partial dissociating gas physics and the chemical property.