摘要
本文讨论了烯丙基氯与三氯硅烷的硅氢化反应的活性铂催化剂的制备、结构和均相催化机理，解释了获得高产率（８５％）反马氏加成规则产物－γ－氯丙基三氯硅烷及其反应时间大大缩短的原因。
In the paper we disscuss the preparation, structure and homogeneous catalytic mechanism of activet platinum catalyst in the addition of silicon hydrides to allyl chloride and trichlorosilane, and explain the facts obtained from the experiment that high yield (85%) of ant-Markovnikov's Rue addition product-γ-chlorpropyltrichlorosilane and the time of reaction shortened into fifteen hours.
基金
安徽省教委自然科学基金
关键词
烯丙基氯
铂催化剂
均相催化
硅氢化反应
氯硅烷
allyl chloride
activet platinum catalyst
homogeneous catalytic mechanism
