甲苯选择性氯化合成对氯甲苯

The Synthesis of Parachlorotoluene by Selective Chlorination of Toluene

综述了国内外甲苯选择性氯化合成对氯甲苯的研究情况,介绍了用氯气、含氯有机化合物和无机氯化物作氯化剂氯化的各种氯化方法,重点介绍了路易斯酸催化剂和含硫助催化剂的催化体系和沸石分子筛催化剂体系,并评价了有关的方法。

The study on synthesis of parachlorotoluene by selective chlorination of toluene in china and overseas was Summariged in this paper. The various chlorinating methods with chlorinating agent chlorine gas, organic chloro-containing compounds and inorganic chloride were introduced. The catalyst systems of lewis acid catalyst and sulfur-containing co-catalyst and zeolites catalyst systems were highlighted. The relevant methods were evaluated.