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有机蒙脱土改性聚氨酯纺丝研究 被引量:6

PREPARATION OF ORGANIC MONTMORILLONITE MODIFIED POLYURETHANE FIBERS
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摘要 Polyurethane/montmorillonite nano-composites were synthesized,and then used for fiber spinning.The viscosity of the spinning solutions,dispersion of montmorillonite in cast films and drawn fibers,as well as the mechanical properties of polyurethane/montmorillonite fibers were investigated.The results indicated that the viscosities of spinning solutions containing montmorillonite were lower than that of the pure polyurethane solution,and the viscosity of spinning solutions increased after standing 24 h at room temperature.TEM images showed that montmorillonite particles were dispersed at the scale from nanometer to micrometer in fiber matrix.Compared with pure PU fibers,the mechanical properties of polyurethane/montmorillonite composite fibers were not improved except that the elongation at break was slightly increased. Polyurethane/montmorillonite nano-composites were synthesized, and then used for fiber spinning. The viscosity of the spinning solutions, dispersion of montmorillonite in cast films and drawn fibers, as well as the mechanical properties of polyurethane/montmorillonite fibers were investigated. The results indicated that the viscosities of spinning solutions containing montmorillonite were lower than that of the pure polyurethane solution, and the viscosity of spinning solutions increased after standing 24 h at room temperature. TEM images showed that montmorillonite particles were dispersed at the scale from nanometer to micrometer in fiber matrix. Compared with pure PU fibers, the mechanical properties of polyurethane/montmorillonite composite fibers were not improved except that the elongation at break was slightly increased.
出处 《高分子学报》 SCIE CAS CSCD 北大核心 2006年第4期645-648,共4页 Acta Polymerica Sinica
基金 国家"973"计划(项目号2003CB615602)资助项目
关键词 蒙脱土 聚氨酯复合物 纺丝 力学性能 粘土分散 Organo-montmorillonite/polyurethane composite, Fiber spinning, Mechanical properties, Clay dispersion
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