期刊文献+

嵌段共聚物微相分离微结构的研究 被引量:1

Study of microphase-separated structure of block copolymers
下载PDF
导出
摘要 用阴离子聚合法合成了系列嵌段共聚物(block copolymer)的薄膜试样(两嵌段的聚苯乙烯(polystyrene)/聚丁二烯(polybutadiene)),用扫描探针显微镜(SPM)和透射电子显微镜(TEM)观测嵌段共聚物的微相分离微结构。 The microstructure and microphase behaviour of block copolymer of polystyrene (PS) and polybutadiene (PB) were studied by transmission electron microscopy and scanning probe microscopy. The composition was varied from 10 wt. % to 35 wt. % PB.
出处 《电子显微学报》 CAS CSCD 2006年第4期353-355,共3页 Journal of Chinese Electron Microscopy Society
关键词 嵌段共聚物 微结构 扫描探针显微镜 电子显微镜 block Copolymer ultrastructure SPM, TEM
  • 相关文献

参考文献8

  • 1Templin M,Franck A,et al.Organically modified aluminosilicate mesostructures from block copolymer phases[J].Science,1997,(278):1795-1798.
  • 2陈宾,张景春,谢续明.多单体熔融接枝聚丙烯的微相分离结构[J].高等学校化学学报,2004,25(8):1572-1575. 被引量:7
  • 3Mani S,Weiss R A,et al.Microstructure of block copolymers of polystyrene and poly(ethylene-alt-propylene)[J].Polymer,1998,39:2023-2033.
  • 4Matsushita Y,Noro A,et al.Effect of composition distribution on microphase-separated structure from diblock copolymers[ J ].Macromolecules,2003,(36):8074 -8077.
  • 5Meyors R A Ed.Encyclopedia of Analytical Chemistry[M].UK:John Wiley & Sons Ltd,2000.V8.
  • 6Hashimoto T,Koizumi S,et al.Observation of "mesh" and "strut" structures in block copolymer/homopolymer mixtures[ J ].Macromolecules,1992,25:1433-1439.
  • 7Khandpur A K,et al.Polyisoprene-polystyrene diblock copolymer phase diagram near the order-disorder transition[J].Macromolecules,1995,28:8796-8806.
  • 8Gong Yumei.Huang Haiying,et al.Inverted to normal phase transition in solution-cast polystyrene-poly (methyl methacrylate) block copolymer thin films[ J ].Macromolecules,2006,39:3369-3376.

二级参考文献14

  • 1Bates F. S.. Science[J], 1991, 251:898-905
  • 2Leibler L.. Macromolecules[J], 1980, 13:1 602-1 617
  • 3ManiS., WeissR. A., HahnS. F. et al.. Polymer[J], 1998, 39: 2 023-2 033
  • 4Kimishima K. , Jinnai H. , Hashimoto T.. Macromolecules[J], 1999, 32:2 585-2 596
  • 5Beyer F. L. , Gido S. P. , Buschl C. et al.. Macromolecules[J], 2000, 33:2 039-2 048
  • 6Hasegawa H. , Tanaka H. , Yamasaki K. et al.. Macromolecules[J], 1987, 20: 1 641-1 645
  • 7Hashimoto T. , Shibayama M. , Kawai H.. Macromolecules[J], 1980, 13: 1 237-1 247
  • 8Li H. G. , Chiba T. . Higashida N. et al.. Polymer[J], 1997, 38: 3 921-3 925
  • 9Orr C. A. , Adedeji A. , Hirao A. et al.. Macromolecules[J], 1997, 30: 1 243-1 246
  • 10Xie Xu-Ming,Chen Nian-Huan,Guo Bao-Hua.et al..PolymerInternational[J],2000,49:1 677-1 683

共引文献6

同被引文献14

  • 1Lee S K, Kim B K. High solid and high stability waterborne polyurethanes via ionic: groups in soft segments and chain termini [J]. Journal of Colloid and Interface Science, 2009, 336( 1 ) : 208 -214.
  • 2Song C M, Ynan Q L, Wang D N. Effect of the content of urea groups on the particle size in water - borne polyurethane, or polyurethane/polyacrylate dispersions [J]. Colloid & Polym. Sci., 2004, 282 (6): 642 -645.
  • 3YangC H, Liu F J, Liu Y P, et al. Hybrids of colloidal silica and water polyurethane [J]. Journal of Colloid and Interface Science, 2006, 32 ( 1 ) : 123 - 132.
  • 4张帆,辛中印,周向东,等.一种可多重固化水性超支化聚氨酯无机纳米材料杂化涂饰剂及其制备方法[P]:CN,101597461A.2009-12-9.
  • 5Decker C, Masson F, Schwalm R. Dual - curing of waterborne urethane - acrylate coatings by UV and themal processing [J]. Schwalm Macromol. Mater. Eng. , 2003, 288(1) : 17 -28.
  • 6Maag K, Lenhard W, Helmut L. New UV curing systems for automotive applications [J]. Pro. Org. Coat., 2000,40 (4) : 93 -97.
  • 7Zhu S W, Shi W F. Flame retardant mechanism of hyperbranched polyure-thane acrylates used for UV curable flame retardant coatings [J]. Polym. Degrad. Stab. , 2002, 75 (3) : 543 - 547.
  • 8Zeng S M, Chert A F, Yao C, et al. Synthesis and properties of hyper- branchen polyurethane with long chain between the branching point [J]. Designed Monmers and Polymers, 2009, 12 (3) : 221 -231.
  • 9Mclean R S, Bryan B S. Tapping mode AFM studies using phase detection for resolution of nanophase in segmented polyurethane and other block copolymer [J]. Macronaolecules, 1997, 30(26) : 8314 -8317.
  • 10赵培仲,王源升,朱金华,花兴艳,文庆珍.聚氨酯弹性体的微相分离对其溶胀和溶解行为的影响[J].高分子材料科学与工程,2008,24(1):71-74. 被引量:5

引证文献1

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部