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ZSM-5型沸石膜反应器在乙苯脱氢反应中的模式 被引量:6

Ethylbenzene dehydrogenation in ZSM-5 zeolite membrane reactor
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摘要 ZSM-5 zeolite membrane reactor was used in ethylbenzene dehydrogenation to styrene under the circumstances of commercial production.The experimental results indicated that the conversion of ethylbenzene in the membrane reactor increased with increasing pressure of the membrane tube.Using the inert sweep gas instead of vacuumizing, the result of long term steady operation under the same condition showed that the selectivity of styrene increased and the conversion of ethylbenzene in the membrane reactor increased by 7.52% in comparison with the fixed-bed reactor. ZSM-5 zeolite membrane reactor was used in ethylbenzene dehydrogenation to styrene under the circumstances of commercial production. The experimental results indicated that the conversion of ethylbenzene in the membrane reactor increased with increasing pressure of the membrane tube. Using the inert sweep gas instead of vacuumizing, the result of long term steady operation under the same condition showed that the selectivity of styrene increased and the conversion of ethylbenzene in the membrane reactor increased by 7. 52% in comparison with the fixed-bed reactor.
出处 《化工学报》 EI CAS CSCD 北大核心 2006年第8期1923-1926,共4页 CIESC Journal
基金 中国石化集团公司重点资助项目(497016).~~
关键词 ZSM-5 沸石膜 乙苯脱氢 膜反应器 ZSM-5 zeolite membrane ethylbenzene dehydrogenation membrane reactor
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参考文献9

  • 1Yan Y,Davis M E,Gavalas G R.Preparation of ZSM-5 membrane by in-situ crystallization on porous α-Al2O3.Ind.Eng.Chem.Res.,1995,34:1652-1661
  • 2张雄福,王金渠.沸石分子筛膜的合成与应用研究进展[J].石油化工,1999,28(4):266-270. 被引量:17
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