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壳聚糖渗透汽化膜分离醇/水的性能Ⅰ.壳聚糖均质膜 被引量:5

ETHANOL-WATER SEPARATION BEHAVIORS OF CHITOSAN PERVAPORATION MEMBRANE: PART Ⅰ THE CHITOSAN HOMOGENEOUS MEMBRANE CROSSLINKED BY SULFURIC ACID
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摘要 研究了壳聚糖(CS)的制膜方法,试制出对高浓度乙醇水溶液的分离具有较好渗透汽化性能的硫酸交联透水膜,该膜对80wt%乙醇水溶液的分离具有最高的PSI值(α×J)。实验还表明膜的分离系数(α)值随乙醇浓度的下降而下降; The chitosan polyacrylonitrile(CS/PAN) composite membrane was prepared and used to separate the ethanol water mixture by pervaporation. The membrane showed higher stability than that of the homogeneous membrane. The permselectivity of the composite membrane can be kept after operating in the low ethanol concentration feed solution. Ten odd kinds of reagents instead of sulfuric acid aqueous solution were used to treat the CS composite membrane. The experiments indicated that the ultra thin composite membrane treated by poly(kalium 4 styrenesulfonate)(PSSK) possessed the best permselectivity, its separation factor and permeability reaching 453 and 170g/m 2h, respectively.
出处 《水处理技术》 CAS CSCD 北大核心 1996年第4期189-194,共6页 Technology of Water Treatment
基金 国家八五攻关项目资助
关键词 复合膜 壳聚糖 渗透通量 composite membrane, chitosan, permeate flux
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