FeCl_3与30% H_2O_2对醇的催化氧化

Catalytic oxidation of alcohols using FeCl_3 and 30% H_2O_2

以FeCl3为催化剂,环境友好的30%H2O2为氧化剂,研究了对甲氧基苯甲醇的催化氧化,考察了影响反应的各种因素,实现了最优条件下其他醇的催化氧化.结果表明,用30%H2O2氧化醇时,FeCl3是较好的催化剂,在温和条件下,一系列醇都可被氧化成相应的羰基化合物.

p-Methoxybenzalcohol is oxidized by 30% H2O2 with the catalysis of FeCl3 under mild condition. The oxidation reaction is well investigated, and the reaction condition is optimized. Other alcohols are also oxidized with high conversion and product selectivity under the optimizing condition. The results indicate that FeCl3 is a promising catalyst for the oxidation of alcohol with 30%H2O2 as oxidant.