摘要
本文报道两个ＣＵ（Ⅰ）－膦配合物ＣＵＣｌ（ＰＰｈ３）３和Ｃｕ２Ｃｌ２（ＰＰｈ３）３的合成、表征。发现它们是光致发光的。研究了其红外、紫外可见的吸收光谱和发射光谱。研究表明，配合物的光谱性质主要来源于配体ＰＰｈ３，Ｃｕ－Ｐ配合对光谱性质的影响不大。
This paper reports the synthesis and characterization of two Cu (Ⅰ ) phosphine complexes CuCl (PPh_3)_3 and Cu_2Cl_2 (PPh_3)_3. It is found that the complexes are photoluminescent. The IR, UV-Vis absorption spectra and emission spectra are investigated. The studies show that the spectroscopic properties are mainly due to the ligand PPh_3, and are not significantly altered upon coordination of Cu-P.
出处
《光谱学与光谱分析》
SCIE
EI
CAS
CSCD
北大核心
1996年第5期10-13,共4页
Spectroscopy and Spectral Analysis
关键词
铜
配合物
三苯基膦
光谱学
Cu(Ⅰ )complex, Triphenylphosphine, Spectroscopy
