DPPZ镉(Ⅱ)配合物的合成及晶体结构

Synthesis and Crystal Structure [(dipyrido[3,2-a:2′,3′-c]phenazine)cadmium] Complex

通过溶剂热合成法制备一种新的化合物Cd(DPPZ)2Cl2,并通过X射线单晶衍射仪对其进行了表征.单晶分析表明:化合物属于单斜晶系,C2/C空间群,a=0.84836(17)nm,b=1.2615(3)nm,c=2.9178(6)nm,α=90.00°,β=92.774(4)°,γ=90.00°,V=3.1191(11)3,Z=4,T=293(2)K,Dc=1.197 cm-1,μ=1.434mm-1,R1=0.01497,wR2=0.3702.

A novel coordination polymer [Cd（DPPZ）2Cl2] n was prepared by hydrothermal synthesis and characterized by single - crystal X - ray diffraction. Single crystal X - ray analysis indicates that this compound crystallizes in monoclinie system, space group C2/e with parameters： a = 0. 84836（17） nm,b= 1. 2615（3） nm, c = 2.9178（6） nm,α = 90.00°,β= 92.774（4）°,γ = 90.00°, V = 3.1191（11） А3, Z = 4, Z = 293（2） K, Dc = 1. 197 cm^-1 ,μ = 1.434 mm^-1, R1 = 0.01497, ωR2 = 0.3702.