摘要
采用水热法制备1,2二-吡啶基乙烷-钼磷酸盐(C12H14N2)2.PMo12O40,并用元素分析,红外光谱和单晶X射线衍射对其进行表征.该晶体属于三斜晶系,P(-1)空间群,晶胞参数a=11.3577(9)A°,b=12.2030(10)A°,c=18.1588(14)A°,α=80.866(2)°,β=78.170(2)°,γ=88.783(2)°,V=2431.9(3)A°3,Z=2,R1=0.0454,wR2=0.0880.该晶体由十二钼磷酸阴离子和质子化的1,2二-吡啶基乙烷分子通过静电引力和氢键相互作用堆积而成.UV-VIS-NIR反射光谱表明,该晶体在4.0—1.5 eV都有较强的选择性吸收.
（C12H14N2）2·PMo12O40 has been obtained via a hydrothermal reaction of H3 [ P（ Mo3O10 ）4 ] · xH2O, ZnO and 1,2-bis（4-pyridyl）ethane. EDS, IR spectra and X-ray crystal structure analysis were carried out to determine its composition and crystal structure. The crystal belongs tomonoclinic space group P （ - 1 ） with lattice parameters n=11.3577（9）A,b=12.2030（10）A,c=18.1588（14）A,a=80.866（2）°,β=78.170（2）°,γ=88.783（2）°,V=2431.9（3）A^3,Z=2,R1=0.0454,wR2=0.0880. （PMo12O40）^4- anions and protonated 1,2-bis（4-pyridyl） ethane pack to construct the crystal structure though electrostatic interactions and hydrogen bonds. Its optical absorptive characteristic is obtained by the measurement of diffuse reflectivity.
出处
《环境化学》
CAS
CSCD
北大核心
2006年第5期619-623,共5页
Environmental Chemistry
