摘要
Fluorescence of Tm^3+/Er^3+ codoped bismuth-silica (BS) glasses and the sensitization of Ce^3+ are investigated, It shows that Ce^3+ codoping with Tm^3+/Er^3+ in BS glasses results in a quenching of Tm^3+ ion emission from ^3F4 to the ^3H6 level. Consequently, the 1.47μm emission occurs after the population inversion between the ^3H4 and ^3F4 levels. Furthermore, the codoped glasses show the broad emission spectra over the whole S and C bands with full-width at half-maximum (FWHM) up to about 119nm, as it combines 1.55μm emission band of Er^3+ with 1.47μm emission band of Tm^3+ under 800hm excitation.
Fluorescence of Tm^3+/Er^3+ codoped bismuth-silica (BS) glasses and the sensitization of Ce^3+ are investigated, It shows that Ce^3+ codoping with Tm^3+/Er^3+ in BS glasses results in a quenching of Tm^3+ ion emission from ^3F4 to the ^3H6 level. Consequently, the 1.47μm emission occurs after the population inversion between the ^3H4 and ^3F4 levels. Furthermore, the codoped glasses show the broad emission spectra over the whole S and C bands with full-width at half-maximum (FWHM) up to about 119nm, as it combines 1.55μm emission band of Er^3+ with 1.47μm emission band of Tm^3+ under 800hm excitation.
基金
Supported by the Natural Science Foundation of Zhejiang Province under Grant No Y104498, the Science and Technology Department of Zhejiang Province under Grant Nos 2005C31014 and 2006C21082.