摘要
A novel coordination ploymer [Cd(HO-BDC)(phen)·H2O]n (where HO-BDC is 5-Hydroxyisophthalic acid and phen is 1,10-phenanthroline) has been synthesized and characterized by elemental analysis, IR spectra and single-crystal X-ray diffraction. The crystal belongs to monoclinic, space group P2/c, with a=0.876 4(2) nm, b=1.233 0(3) nm, c=1.761 2(4) nm, β=109.152(9)°, V=1.797 8(7) nm3, Z=4, Mr=490.73, Dc=1.813 g·cm-3, F(000)=976, μ=1.258 mm-1, the final R=0.043 8 and wR=0.098 9 for 2 880 observed reflections with I>2σ(I). The structural analysis shows that the complex has a one-dimensional chain structure. CCDC: 609770.
A novel coordination ploymer [Cd（HO-BDC）（phen）·H2O]n （where HO-BDC is 5-Hydroxyisophthalic acid and phen is 1,10-phenanthroline） has been synthesized and characterized by elemental analysis, IR spectra and single-crystal X-ray diffraction. The crystal belongs to monoclinic, space group P2/c, with a=0.876 4 （2） nm, b= 1.233 0（3） nm, c=1.761 2（4） nm, β=109.152（9）°, V=1.797 8（7） nm^3, Z=4, Mr=490.73, Dc=1.813 g·cm^-3, F（000）= 976,μ=1.258 mm^-1, the final R=0.043 8 and wR=0.098 9 for 2 880 observed reflections with I〉2σ （I）. The structural analysis shows that the complex has a one-dimensional chain structure. CCDC： 609770.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2006年第10期1847-1851,共5页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金资助项目(No.20571039)
国家自然科学基金重大项目(No.90101028)
教育部博士点专项科研基金(No.20050284031)
江苏省自然科学基金(No.BK2006124)
