摘要
The title complex [Sm(o-MOBA)3(phen)·H2O]2·4H2O has been synthesized by the reaction of SmCl3·6H2O with o-methoxybenzoic acid and 1,10-phenanthroline in 1∶3∶1 molar ratio. The crystal structure was determined by X-ray single crystal diffraction. The crystal belongs to triclinic system, space group P1 with a=1.203(10) nm, b=1.293(10) nm, c=1.306(11) nm, α=64.50(10)°, β=81.93(10)°, γ=74.81(10)°. The molecular structure shows that the Sm3+ ion coordinates to nine atoms. The carboxylate groups are bonded to the samarium ion in three modes: monodentate, bidentate chelating, tridentate chelating-bridging. CCDC: 603740.
The title complex [Sm（o-MOBA）3（phen）·H2O]2·4H2O has been synthesized by the reaction of SmCl3·6H2O with o-methoxybenzoic acid and 1,10-phenanthroline in 1：3：1 molar ratio. The crystal structure was determined by X-ray single crystal diffraction. The crystal belongs to triclinic system, space group P1 with a=1.203（10） nm, b=1.293（10） nm, c=1.306（11） nm,α=64.50（10）°, β=81.93（10）°, γ=74.81（10）°. The molecular structure shows that the Sm^3＋ ion coordinates to nine atoms. The carboxylate groups are bonded to the samarium ion in three modes： monodentate, bidentate chelating, tridentate chelating-bridging. CCDC： 603740.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2006年第10期1905-1907,共3页
Chinese Journal of Inorganic Chemistry
基金
河北省自然科学基金资助项目(No.202140,No.203148)
河北省教育厅自然科学基金资助项目(No.2004325)
河北师范大学自然科学基金资助项目(No.L2005Y12)
