摘要
A mixed complex [Zn(CF3COO)2(C7H6NS)2] was synthesized based on the reaction of Zn(CF3COO)2 and 2-aminobenzothiazol (C7H6NS) in methanol. The structure of the complex was characterized by elemental analysis, IR, 1H NMR and thermal analysis. The crystal structure of the complex was determined by X-ray single crystal diffraction. The crystal belongs to monoclinic system with space group C2/c, a=3.174 3(9) nm, b=1.010 0(3) nm, c=1.723 1(5) nm, β=118.841(4)°, V=4.839(2) nm3; Dc=1.625 g·cm-3; Z=8; F(000)=2 368; μ=1.266 mm-1. CCDC: 600233.
A mixed complex [Zn（CF3COO）2（C7H6NS）2] was synthesized based on the reaction of Zn（CF3COO）2 and 2-aminobenzothiazol （C7H6NS） in methanol. The structure of the complex was characterized by elemental analysis, IR, ^1H NMR and thermal analysis. The crystal structure of the complex was determined by X-ray single crystal diffraction. The crystal belongs to monoclinic system with space group C2/c, a=3.174 3 （9） nm, b=1.010 0（3） nm, c = 1.723 1 （5） nm, β= 118.841 （4）°, V =4.839 （2） nm^3; Dc= 1.625 g·cm^-3; Z=8; F（000）=2 368; g= 1.266 mm^-1. CCDC： 600233.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2006年第10期1925-1928,共4页
Chinese Journal of Inorganic Chemistry
基金
江苏省自然科学基金资助项目(No.BK2005045)
江苏省高校自然科学研究计划资助项目(No.05KJB150003
01KJB150011)
江苏省海洋生物技术重点建设实验室研究基金资助课题(No.2005HS010)
淮海工学院学科基金资助项目(No.XK200310)
关键词
Zn(Ⅱ)配合物
谱学表征
晶体结构
Zn（Ⅱ） complex
spectral characterization
crystal structure
