氯化物催化合成甲、乙、丙酸异戊酯的活性和机理探讨

THE CATALYTIC ACTIVITY OF CHLORIDES IN THE SYNTHESIS OF ISOAMYL FORMATE,ACETATE AND PROTIONATE

本文分别用氯化铁、氯化铝和氯化铜催化合成甲、乙、丙酸异戊酯，实验证明氯化铁、氯化铝有较高催化活性，对五个碳以下的有机酸和醇的酯化活性较高，并对其机理进行了探讨。

Using ferric chloride,aluminum chloride and cupric chloride as catalytics in the synthesis of isoamyl formate,acetate and propionate. The results shown that Fecl3 and Alcl3 have good catalytic activities. Authors consider that organic acids and alcohols having carbon atoms lesser than 6 would be easily esterified by these chlorides.The mechanism of is discussed.