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恒波长同步荧光同时测定1,2-苯并蒽、苯并[K]芴和3.4,8.9-二苯并芘

Constant-Wavelength Synchronous Fluorescence Spectrometry for Simultaneous Determination of 1,2-Benzoanthracene, Benzo[ K] fluorene and 3.4,8.9-Dibenzopyrene
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摘要 为检测多环芳烃,采用了1,2-苯并蒽(1,2-BA)、苯并[K]芴(BkF)和3.4,8.9-二苯并芘(DBP)恒波长同步荧光分析法,选择波长差△λ=30nm,只需一次扫描,就可实现3组分的同时鉴别和定量测定.该方法简便、快速、灵敏,无需预分离,用于自来水、海水和溪水的分析,取得了良好的效果. In order to detect PAHS, a new method of constant-wavelength synchronous fluorescence to determine 1,2-benzoanthracene, benzo [k]fluorene and 3.4, 8.9-dibenzopyrene simultaneously is suggested. Only a single scan is needed for the simultaneous identification and quantitative determination of the three PAHS when △λ = 30 nm is chosen. This method is simple, rapid and sensitive, and doesn' t need separation. It is used to analyze tap water, sea water, brook water, the good results are get.
机构地区 莆田学院药学系
出处 《华北水利水电学院学报》 2006年第4期101-103,共3页 North China Institute of Water Conservancy and Hydroelectric Power
关键词 1 2-苯并蒽 苯并[K]芴 3.4 8.9-二苯并芘 同步荧光 1,2- benzoanthracene benzo[ K ] fluorene 3.4,8.9- dibenzopyrene synchronous fluorescence spectrometry
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参考文献4

  • 1Lubov O, Mikhail S, Grigoriy T, et al. On-line Solid-phase Extraction and HPLC Determination of Polycyclic Aromatic Hydrocarbons in Water Using Fluorocarbon Polymer Sorbents[J].Analytica Chimica Acta, 2005,538 : 35-40.
  • 2Possanzini M, Palo V D, Gigliucci P, et al. Determination of Phase-distributed PAH in Romeambient Air by Denuder/GCMS Method [ J ]. Atmospheric Environment, 2004, 38 : 1727-1734.
  • 3Capelo J L, Galesio M M, Felisberto G M, et al. Micro-focused Ultrasonic Solid-liquid Extraction (uFUSLE) Combined with HPLC and Fluorescence Detection for PAHs Determination in Sediments: Optimization and Linking with the Analytical Minimalism Concept[J] .Talanta ,2005, 66 : 1272-1280.
  • 4Patra D, Mishra A K. Recent Developments in Multi-component Synchronous Fluorescence Scan Analysis[J]. Trac Trends in Analytical Chemistry, 2002, 21 (12) : 787 - 798.

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