摘要
合成了配合物[Ni(C13H10N3O2)2].0.25CH3OH(C13H10N3O2=吡啶-2-甲醛缩水杨酰肼),并利用X-射线单晶衍射仪确定了其结构。该配合物属单斜晶系,空间群为P21/n。在配合物中,每个Ni(Ⅱ)离子与两个吡啶-2-甲醛缩水杨酰肼的四个氮原子和两个氧原子配位,形成了畸变的八面体结构。
The complex [Ni（C13H10N3O2）2]·0.25 CH3OH
（C13H10N3O2 = pyridine-2-carboxaldehyde salicylhydrazone） was synthesized and characterized by X-ray diffraction. The crystal belongs to a monoclinic system, space group P2（ 1）/n. In the complex, each Nickel（ Ⅱ ） ion is six coordinated by two ligands on distorted octahedron geometry. The neighboring molecules are connected by the hydrogen bonds forming a dimeric structure.
出处
《安阳师范学院学报》
2006年第5期84-86,共3页
Journal of Anyang Normal University
基金
广西科学基金资助项目(0342025)
高等学校优秀青年教师教学科研奖励计划项目
