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氨纶用聚酯二醇的研究 被引量:3

Research on Polyesterglycol for Polyurethanefiber
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摘要 本文研究了聚酯二醇的生产工艺,重点研究了反应温度对生产工艺的影响以及原料已二酸与二元醇的投料比对产品酸值和羟值的影响,催化剂对产品质量的影响,并对产品着色原因进行了探讨。 This paper researched the production process of polyester glycol, emphasized research on the effect of reaction temperature on production process, the effect of charge ratio of acidic acid and glycol on product acid number and hydroxyl number and the effect of catalyst on product quality, discussed the coloring cause of product.
作者 杨红
出处 《广东化工》 CAS 2006年第10期10-14,共5页 Guangdong Chemical Industry
关键词 氨纶 聚酯二醇 温度 投料比 催化剂 着色原因 polyurethanefiber polyesterglycol temperature charge ratio catalyst coloring cause
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同被引文献25

  • 1孙彦璞,杨文远.聚酯二元醇合成工艺的研究[J].宁夏工程技术,2005,4(3):262-264. 被引量:9
  • 2朱蔚璞,童晓薇,沈之荃.三氟甲磺酸稀土催化ε-己内酯开环聚合[J].高等学校化学学报,2007,28(6):1186-1188. 被引量:8
  • 3Takasu A, Oishi Y, Iio Y, et al. Synthesis of alphatic polyesters by direct polyesterification of dicarboxylic acids with diols under mild conditions catalyzed by reusable rare-earth triflate [ J ]. Macromolecules, 2003, 36 : 1772 - 1774.
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  • 5Ishihara K, Kubota M, Kurihara H, et al. Scandium trifluoromethanesulfonate as an extremely active Lewis acid catalyst in acylation of alcohols with acid anhydrides and mixed anhydrides [ J ]. J Org Chem, 1996, 61:4560 - 4567.
  • 6Takasu A, Iio Y, Oishi Y, et al. Environmentally benign polyester synthesis by room temperature direct polycondensation of dicarboxylic acid and diol [ J ]. Macromolecules ,2005,38 : 1048 - 1050.
  • 7Takasu A, Oishi Y, Iio Y, Inai Y, Hirabayashi T. Macromolecules [ J ] ,2003,36 : 1 772
  • 8Ishihara K,Kubota M,Kurihara H,Yamamoto H. J Am Chem Soc[J] ,1995,117:4 413
  • 9Ishihara K, Kubota M, Kurihara H,Yamamoto H. J Org Chem[ J] , 1996,61:4 560
  • 10Takasu A, Iio Y, Oishi Y, Narukawa Y, Hirabayashi T. Macromolecules [ J ] ,2005,38 : 1 048

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