摘要
以叶甲基苯乙烯(α-Ms)为原料,以阳离子交换树脂、活性白土等为催化剂分别合成了α-MS环二聚体,线性2-3聚体,5-8聚体,2.4-二苯基4-甲基.戊烯-(1)等化合物。以阳离子交换树脂为催化剂,催化剂用量为原料质量的5%,140℃,反应时间4h,得α-MS环二聚体,收率87.2%,并以MS、IR、NMR测试技术表征了化合物结构。
The a-methylstyrene cyclic dimer, liner dimer-trimer, pentamer-octamer, and 2,4-diphenyl-4- methyl-amylene-( 1 ) were synthesized from α-methylstyrene(α-MS) with activated clay or strong acidic cation exchange resin as catalyst. With strong acidic cation exchange resin as catalyst, the reaction temperature was 140℃, the quantity of catalyst was 0. 05 times as much as the amount of α-MS, and the reaction time was 4 h, the yield of α-MS cyclic dimer was 87.2%. The structure of the products was determined by IR, MS and NMR.
出处
《应用化学》
CAS
CSCD
北大核心
2006年第9期1063-1065,共3页
Chinese Journal of Applied Chemistry