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纳米Al_2O_3掺杂对Ce_(0.8)Y_(0.2)O_(2-δ)晶界离子电导的影响 被引量：1

Effect of Nano-Al_2O_3 Doping on Grain Boundary Conduction of Ce_(0.8)Y_(0.2)O_(2-δ) Electrolyte
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摘要 研究了纳米A l2O3第2相掺杂对Ce0.8Y0.2O2-δ固体电解质晶界离子电导率的影响。结果发现,掺杂少量纳米A l2O3可降低固体电解质的晶界电导活化能,中低温下的晶界离子电导率显著上升。分析表明,掺杂第2相在晶界处的偏聚改善了晶界的离子导电通道结构,是导致晶界离子电导率上升的主要原因。 The effect of nano-Al2O3 doping on the grain boundary （GB） conductivity of polycrystalline Ce0.8Y0.2O2-δ was investigated. It was found that the addition of Al2O3 leads to a decrease in GB activation energy, and an increase in the GB conductivity at low and moderate temperatures obviously. The results indicate that the effect is attributed to the improvement of oxygen-ion migration structure in the grain boundary due to the doping of A1203.
作者 刘毅
机构地区 贵州大学理学院
出处 《应用化学》 CAS CSCD 北大核心 2006年第9期978-981,共4页 Chinese Journal of Applied Chemistry
基金 贵州省科技厅自然科学基金项目(黔科合J字(2005)2091号)
关键词 Ce0.8Y0.2O2-δ固体电解质 AL2O3 晶界离子电导率 Ce0.8 Y0. 2 O2 - δ, A12O3, grain boundary conductivity
分类号 O614.3 [理学—无机化学] TQ174 [化学工程—陶瓷工业]
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  • 1Butler E P,Drennan J.J Am Ceram Soc[J],1982,65:474
  • 2Rizea A,Chirlesan D,Petot C,et al.Solid State Ionics[J],2002,146:341
  • 3Navarro L,Marques F,Frade J.J Electrochem Soc[J],1997,144:267
  • 4Godickemeier M,Sasak K,Gauckler L J.J Electrochem Soc[J],1997,144:1 635
  • 5Inaba H,Tagawa H.Solid State Ionics[J],1996,83:1
  • 6Gerhardt R,Snowick A,Mochel M E,et al.J Am Ceram Soc[J],1986,69:641
  • 7Zhang T S,Ma J,Kong L B,et al.Solid State Ionics[J],2004,167:203
  • 8Cheng J G,Zha S W,Huang J,et al.Mater Chem Phys[J],2003,78:791
  • 9Badwal S P S.Solid State Ionics[J],1995,76:67
  • 10Guo X.Solid State Ionics[J],1997,96:247

同被引文献18

  • 1Tianmin H, Huang Y I., He Q, et ai. The effects on the structures and properties in the oxide-ion conductor La2Mo2O9 by partial substituting Ba for La[J]. Alloys and Compounds,2004,388 : 145-152.
  • 2Wang X P, Fang Q F, Li Z S, et al. Dielectric relaxation studies of Bi-doping effects on the oxygenion diffusion in La2 xBix Mo2O9 oxide-ion conductors [J]. Appl. Phys. Lett. ,2002,81:3 43-3 436.
  • 3Lacorre P, Goutenolre F, Bohnke O, et al. Designingfast oxide ion conductors based on La2Mo2O9 [J]. Nature, 2000,404 : 856-858.
  • 4Wang X P, Cheng Z J, Fang Q F. Influence of potassium doping on the oxygen-ion diffusion and ionic conduction in the La2Mo2O9 oxide-ion conductors [J]. Solid State Ionics,2005,176 : 761-765.
  • 5Wang X P, Fang Q F. Effects of Ca doping on the oxygen ion diffusion and phase transition in oxide ion conductor La2Mo2O9 [J]. Solid State Ionics,2002,146:185-193.
  • 6Fang Q F, Wang X P, Li Z S, et al. Relaxation peaks associated with the oxygen-ion diffusion in La2-x Bix Mo2O9 oxide-ion conductors[J ]. Materials Science and Engineering A, 2004,370 : 365 369.
  • 7Yang J H, Gu Z H, Wen Z Y, et al. Preparation and characterization of solid electrolytes La2-x AxMo2-yWyO9 (A=Sm, Bi)[J]. Solid State Ionics, 2005,176 : 523-530.
  • 8Georges S, Goutenoire F, Ahorfer F, et al. Thermal, structural and transport properties of the fast oxide-ion conductors La2-x Rx Mo2 O9 ( R = Nd, Gd, Y)[J]. Solid State Ionics,2003,161:231 -241.
  • 9Marozau I P, Marrero-Lopez D, Shaula A L, et al. Ionic and electronic transport in stabilized β-La2 Mo2 O9 electrolytes [J]. Electrochimica Acta,2004,49:3 517- 3 524
  • 10Arulraj A, Goutenoire F, Tabellout M, et al. Aynthese and characterization of the anionic conductor system La2Mo2O9-0.5xFx(x=0.02-0.03) [J]. Chem. Mater. ,2002,14:2 492-2 498.

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应用化学
2006年 第9期

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