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硅胶表面替米考星分子印迹聚合物的制备 被引量：4

Grafting of Tilmicosin molecularly imprinted polymer on silica supports
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摘要 A molecularly imprinted polymer(MIP)was synthesized successfully through grafting of molecularly imprinted polymer on silica supports by using Tilmicosin as templates,methacrylic acid as a functional monomer and thylene glycol dimethacrylate as crosslinker.The adsorption behavior of Tilmicosin-MIP was preliminarily investigated. A molecularly imprinted polymer（MIP） was synthesized successfully through grafting of molecularly imprinted polymer on silica supports by using Tilmicosin as templates, methacrylic acid as a functional monomer and thylene glycol dimethacrylate as crosslinker. The adsorption behavior of Tilmicosin - MIP was preliminarily investigated.
作者 刘亚 杜振霞 杨俊佼
机构地区 北京化工大学理学院
出处 《化学研究与应用》 CAS CSCD 北大核心 2006年第10期1186-1188,共3页 Chemical Research and Application
关键词 替米考星 分子印迹 硅胶 接枝 吸附 Tilmicosin molecularly imprinted polymer （MIP） silica, grafting adsorption
分类号 O632.52 [理学—高分子化学]
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参考文献8

  • 1Sulitzky C,Ruckert B,Hall A J,et al.Grafting of Molecularly Imprinted Polymer Films on Silica Supports Containing Surface-Bound Free Radical Initiators[J].Macromol 2002,35,79-91.
  • 2Quaglia M.Lorenzi E D,Sulitzky C,et al.Surface initiated molecularly imprinted polymer films:a new approach in chiral capillary electrochromatography[J].Analyst,2001,126,1495-1498.
  • 3Sergeyeva T A.Matuschewski H,Piletsky S A,et al.Molecularly imprinted polymer membranes for substance-selective solide-phase extraction from water by surface photo-grafting polymerization[J].Chrom.A,2001,907,89-99.
  • 4Yan L,Chenxi L,Hesheng Z,et al,Study on the mechanism of chiral recognition with molecularly imprinted polymers[J].Amalytica Chimica Acta,2003,489,33-43.
  • 5Bures P.Yanbin H,Oral E,et al,Surface modifications and molecular imprinting of polymers in medical and pharmaceutical applications[J].Controlled Release 2001,72,25-33.
  • 6Liang E,Yongjun L,Xiaodong Z,The fabrication and characterization of a formaldehydeodor sensor using molecularly imprinted polymers[J].Colloid and Interface Science 2005,284,378-382.
  • 7Meyer T,Spange S,Hesse S,et al,Radical Grafting Polymerization of Vinylformaminde with Functionalized Silica Particles[J].Macromol.chem.phys.2003.204,725-732.
  • 8Simionescu Cr.Sik K G,Com ɑ..nit ɑ..E,Synthesis and Characterization of 4,4′-AZO-BIS-(4-Cyanovaleryl)-BIS-(m-Chlorobenzoyl)Diperoxide[J],J.Eur.Polym.1984,20,No.5.467-470.

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化学研究与应用
2006年 第10期

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