4-氯苯基二苯基硫六氟磷酸盐的合成

Synthesis of(4-chlorophenyl)diphenylsufonium hexafluorophosphate

In this paper,4,4’-dichlorophenyliodonium hexafluorophosphate was synthesized through 4 step reactions.The target product was novel cationic photoinitiator.The structure of the compound was identified by UV,IR,（）1H-NMR,and MS.The optimal operation conditions were determined through orthogonal layout expriment.4,4’-Dichlorophenyliodonium hexafluorophosphate 4.95g（10mmol）,diphenyl sulfide 10ml（6mmol）and catalyst 3×10-4mol were reacted at 120℃ for 3 h,and the yield was 87.9%.

In this paper, 4,4＇ - diehlorophenyliodonium hexafluomphosphate was synthesized through 4 step reactions. The target product was novel cationic photoinifiator. The structure of the compound was identified by UV, IR, ^1H -NMR, and MS. The optimal operation conditions were determined through orthogonal layout expriment. 4,4 ＇ - Diehlorophenyliodonlum hexafluorophosphate 4. 95g（10mmd）, diphenyl suhqde 10ml （6aunol）and catalyst 3 × 10^-4 mol were reacted at 120℃ for 3 h, and the yield was 87.9%.