摘要
综述了由热致相分离法制备多孔膜的成膜机理.分析了由Gauss曲率的特性决定的分为椭圆形、抛物线形和双曲形的孔结构.建立了孔结构和相分离动力学过程:成核、聚结、旋节线分相之间的关系.
Formation mechanisms of the porous membranes, which were prepared by thermal induced phase separation, were reviewed. Pore structures were classified as three types: elliptic, parabolic and hyperbolic, by the characterization of their Gaussian curvatures. Relationship between the pore structure and the kinetics process of phase separation (nucleation, growth and coalesce) was also established.
出处
《膜科学与技术》
CAS
CSCD
北大核心
2006年第5期93-98,共6页
Membrane Science and Technology
基金
国家重点基础研究发展计划资助项目(2003CB615701)
关键词
高分子微孔膜
热致相分离
热力学
相变动力学
微孔结构
porous membranes
thermal induced phase separation
thermodynamics
kinetics process of phase separation
porous structure