期刊文献+

超临界CO_2络合反应分离痕量重金属离子的研究进展

Research Development of Separating Trace Heavy Metal Ions from CO_2 in Supercritical Phase by Using Complex Reaction
下载PDF
导出
摘要 超临界络合反应分离技术是近年来发展起来的一项新技术。本文介绍了超临界络合反应分离技术的原理、分离过程、目前已开发出的络合剂、络合剂的选择原则以及影响因素,指出了当前超临界络合反应分离中存在的问题及发展方向。 Separation by using supercritical complex reaction is a new technique developed in recent years. In this paper, the mechanism and process of separation with supercritical complex reaction as well as developed complex agent, the selection principles of the complex agent and influence factors were introduced. Moreover, the problems existed in the separation process with supercritical complex reaction and developing direction of this technique were indicated.
出处 《医药工程设计》 2006年第5期1-4,共4页 Pharmaceutical Engineering Design
基金 湖北省教育厅科学研究计划项目(2003B002)
关键词 超临界CO2 络合反应 分离 痕量重金属 SupercriticalCO2 Complex reaction Separation Trace heavy metal ion
  • 相关文献

参考文献11

  • 1Wai CM, Wang S. Supereritical fluid extraction: metals as complexes[J]. Chrcalaatogr A, 1997, 785(1-2): 369-383.
  • 2郎庆勇,魏建谟.超临界流体萃取技术的应用及展望[J].岩矿测试,1998,17(3):216-223. 被引量:9
  • 3Laintz K E,Wai C M,Yonker C R,et al. Extraction of Metal Ions from Liquid and Solid Materials by Supercritical Carbon Dioxide[J]. Anal.Chem, 1992,64:2875-2878.
  • 4Wang J, Marshall W D. Recovery of Metals from Aqueous Media by Extraction with Supercritical Carbon Dioxide[J]. Anal Chem., 1994,66:1658-1663.
  • 5Yazdi AliV, Beckman EJ. Design of highly CO2-solublechelating agents[J]. 2 Effect of chelate structure and process parameters on extraction efficiency[J], Ind.Eng Chem Res, 1997, 36(6): 2368- 237.
  • 6Yoshihiro M, Shuichi I,Takayuki S, et al. Solubility of Organophorus Metal Extractants in Supercritical Carbon Dioxide [J]. Anal Chem,1998,70(4): 774-779.
  • 7Wang S F, Elshani S, Wai CM.Selective Extraction of Mercury with Ionizable Crown Ethers in Supercritical Carbon Dioxide[J]. Anal Chem, 1995, (67): 919-923.
  • 8Smart NG, Carleson TE, Elshaui S, et al. Extraction of toxic heavy metals using supercritical fluid carbon dioxide containing organophosphorus reagents[J], Ind Eng Chem Res, 1997, 36(5): 1819-1826.
  • 9Liu Y, Lopez-Avilia V, Alcaraz M, et al. Determination of Metals in Solid Samples by Complexation-Supercritical Fluid Extraction and Gas Chromatography-Atomic Emission Detection[J]. Chromatogr Sci, 1993, 31: 310-316.
  • 10Wang J, Marshall W D. Metal speciation by supercritical fluid extraction with on-line detection by atomic absorption spectrometry[J].Anal Chem, 1994, 66: 3900-3907.

二级参考文献5

  • 1Wai C M,Talanta,1993年,40卷,9期,1325页
  • 2DeSimone J M,Science,1992年,257卷,945页
  • 3Laintz K E,J Supercritical Fluids,1991年,4卷,3期,194页
  • 4Toews K,Anal Chem,1995年,67卷,22期,4040页
  • 5Lin Y,Anal Chem,1993年,65卷,18期,2549页

共引文献25

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部