期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

FOX-7的热分解动力学和机理研究 被引量：9

Study on the Thermal Decomposition Kinetics and Mechanism of FOX-7
下载PDF
导出
摘要 使用原位热红外光谱技术对FOX-7热分解全过程的气相和凝聚相产物进行了原位在线检测,通过非等温热红外动力学处理技术,获得了热分解过程中各特征官能团的断裂分解活化能:C-N键:181.7kJ·mol-1,-NO2键:235.8kJ·mol-1,N-H键:170.7kJ·mol-1。提出了FOX-7可能的两步热分解机理:第1阶段是分子共轭键、分子间(内)氢键的断裂、硝基和亚硝基重排“脱硝”释放出NO;第2阶段是残余碎片分解释放出HCN和NH3。 The whole process of the thermal decomposition of FOX-7 was investigated by thermolysis in-situ cell rapid man IR. The activation energy of C-N,-NO2, -NH is： 181.7kJ·mol^-1, 235.8kJ ·mol^-1 , 170.7kJ ·mol^-1 , which is obtained by using thermo-IR isothermal kinetic method. Two steps appears in thermal decomposition process of FOX-7. In the frist step the hydrogen bond dissociation and the isomerization of the -NO2 group occur and NO is released. The second step concludes the dissociation of the main bond of FOX-7 and at the same time HCN, NH3 are released.
作者 金朋刚 常海 陈智群 刘子如 潘清
机构地区 西安近代化学研究所
出处 《火工品》 CAS CSCD 北大核心 2006年第2期20-24,共5页 Initiators & Pyrotechnics
基金 国防火炸药中青年创新基金课题
关键词 红外光谱分析 FOX-7 原位热红外光谱分析 热裂解质谱 Infrared spectroanalysis FOX-7 In-situ thermal infrared spectroanalysis Thermal decomposition
分类号 TQ560.721 [化学工程—炸药化工] O657.33 [理学—分析化学]
  • 相关文献

参考文献5

  • 1蔡华强,舒远杰,郁卫飞,曾贵玉,程碧波.1,1-二氨基-2,2-二硝基乙烯的研究进展[J].含能材料,2004,12(2):124-128. 被引量：19
  • 2Coats A. W. and Redfern J. P. Kinetic parameters from thermogravimetric data[J].Nature, 1964, 201(4914): 68～69.
  • 3谢晶羲,常俊标,王绪明.红外光谱在有机化学和药物化学中的应用[M].北京:科学出版社,2001.
  • 4B.Brill ,Kenneth J.James.Kinetics and hechanisms of thermal decomposition of nitzoazomatic explosives[J].Chem. Rev,1993,93:2 667～2 692
  • 5Asta. G. Lou. M. Lulu, H.etal.Proposed mechanism of 1,1 -diamino-2,2-dinitroethylene decomposition : a density functional theory study [J].J. Phys. Chem,A ,1999,(103):11 045～11 051.

二级参考文献36

  • 1Sandberg C ,Latypov N,Goede P,et al. Acid-base characteristics of FOX-7 and its monohydrazo analogue [ A ].32th Int. Annu. Conf. ICT[C] ,2001.
  • 2Bellamy A J,Goede P, Sandberg C, et al. Substitution reactions of 1, 1-diamino-2, 2-dinitroethylene ( FOX-7 )[A]. 33th Int. Annu. Conf. ICT[C] ,2002.
  • 3Oestmark H, Langlet A, Bergman H, et al. FOX-7 - A new explosive with low sensitivity and high performance [ A ]. Proc. 11 th Detonation ( Int. ) Symposium [ C ],Snowmass, CO, 1998.
  • 4Doll D W,Hanks J M,Niles J H,et al. Insensitive composition B replacement[A]. Proc. of 1999 Insensitive Munitions and Energetic Materials Technology Symposium [ C ],Tampa, Florida, USA, 1999.
  • 5Eldsater C, Edvinsson H,Johansson M, et al. Formulation of PBX' s based on 1, 1-diamino-2, 2-dinitroe thylene(FOX-7) [A]. 33th Int. Annu. Conf. ICT[C] ,2002.
  • 6Asta G, Lou M, Lulu H, et al. Proposed mechanism of 1,1-diamino-dinitroethylene decomposition: a density functional theory study [ J ]. J. Phys. Chem. , 1999, 103(50): 11045-11051.
  • 7Karlsson S, Oestmark H, Eldsater C, et al. Detonation and sensitivity properties of FOX-7 and formulations containing FOX-7 [ A ]. 12th Detonation ( Int. ) Symposium [ C ], San Diego, California, 2002.
  • 8Latypov N V,Bemm J,Langlet A,et a1.Synthesis and reactions of 1,1-diamino-2,2-dinitroethylene[J].Tetrahedton,1998,54:11525—11536.
  • 9Politzer P,Concha M C, Grice M E,et al. Computational investigation of the structures and relative stabilities of amino/nitro derivatives of ethylene [ J ]. Theochem, 1998,452(1 -3) : 75 -83.
  • 10Dorsett H,White A. Overview of molecular modelling and ab initio molecular orbital methods suitable for use with energetic materials [ A ]. Quantum Chemistry meeting of the 14th AIP Congress [ C ] , Adelaide, South Australia, December,2000.

共引文献18

同被引文献67

引证文献9

二级引证文献33

火工品
2006年 第2期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部