摘要
氟两相体系是一种新的相分离和固定化技术,它实现了均相反应多相化,只需经过简单的相分离即可实现反应产物的分离、提纯、和催化剂的再生.本文介绍了氟两相体系的特点并对氟两相体系在烯烃的氢甲酰化、酯化反应以及其它有机反应中的广泛应用进行了综述.
The Fluorous biphase system represents a new phase separation and immobilization technique, which makes homogeneous catalysis and heterogeneous separation possible. The organic reaction products can be readily separated and catalyst can be recovered by easy phase separation. The characteristics of FBS are introduced and numerous applications of FBS in hydroforylation, esterification and other organic reactions are discussed in the article.
关键词
氟两相体系
氟代催化剂
绿色化学
有机合成
Fluorous biphase systems
Fluorous catalysts
Green chemistry
Organic synthesis
