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Bi_2V_(0.9)Co_(0.1)O_(5.5-δ)的EDTA-柠檬酸盐法合成与氧离子导电性能 被引量：2

EDTA-Citrate Method Synthesis and Oxygen Ionic ConductingProperties of Bi_2V_(0.9)Co_(0.1)O_(5.5-δ)
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摘要 采用EDTA-柠檬酸盐法合成Bi_2V_(0.9)Co_(0.1)O_(5.5-δ)超细粉体,采用TG-DSC、XRD、SEM等测试方法对粉体的合成过程、晶体结构和颗粒形态进行了表征。研究结果表明,经450℃热处理可以得到具有单一Aurivillus结构的超细粉体(约为200nm)。在620℃下烧结3h可制备出致密的陶瓷样品,陶瓷样品的平均晶粒粒径约为3μm,相对密度达到94.5%。采用交流阻抗谱法研究了Bi_2V_(0.9)Co_(0.1)O_(5.5-δ)陶瓷的氧离子导电性能,发现在600℃时Bi_2V_(0.9)Co_(0.1)O_(5.5-δ)陶瓷的氧离子电导率达1.0×10-1S·cm-1。 Bi2V0.9Co0.1O5.5-δ powder was synthesized by an EDTA-citrate process. The crystal structure and morphology of synthesized powder were characterized by TG-DSC, XRD and SEM. The results indicate that fine and uniform powder （about 200nm） with a pure Aurivillius structure was produced by calcining at 450℃ for lh. The ceramic specimen sintered at 620℃ for 3h shows a dense microstructure with an average grain size of about 3 μm and a relative density of 94.5%. The oxygen ionic conducting properties of the ceramic specimen were investigated by AC impedance spectroscopy. The specimen exhibits an oxygen ionic conductivity of 1.0 × 10^-1S·cm^-1 at a measuring temperature of 600℃.
作者 徐开群 张枫 徐庆 陈文 黄端平 刘茜
机构地区 武汉理工大学材料科学与工程学院
出处 《硅酸盐通报》 CAS CSCD 北大核心 2006年第5期74-78,共5页 Bulletin of the Chinese Ceramic Society
基金 国家教育部新世纪优秀人才支持计划资助项目(NECT-04-0724) 国家教育部留学回国人员科研启动基金资助项目(2004-527).
关键词 EDTA-柠檬酸法 Bi2V0.9Co0.1O5.5-δ 氧离子电导率 Aurivillus结构 EDTA-citrate process Bi2V0．9Co0．1O5．5-δ oxygen ionic conductor Aurivillius structure
分类号 TQ174.758 [化学工程—陶瓷工业]
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参考文献20

  • 1Achary S N,Mathews M D,Patwe S J,et al.High-temperature X-ray diffraction and dilatometric studies on some oxygen ion conducting compounds[J].Journal of Materials Science Letters,1999,18:355-357.
  • 2Chadwick A V,Maltese C colli C,Morrison G,et al.EXFS studies of the cation site in BIMEVOX fast-ion conductors[J].Solid State Ionics,1999,119:79-84.
  • 3Yaremchenko A A,Kharton V V,Naumovich E N,et al.Oxygen ionic and ectronic conductivity of La-doped BIMEVOX[J].Solid State Ionics,1998,111:227-236.
  • 4Abrahams I,Krok F,Nelstrop J A G.Defect structure of quenched γ-BICOVOX by combined X-ray and neutron powder diffraction[J].Solid State lonics,1996,90:57-65.
  • 5Lazure S,Vernochet Ch,Vannier R N,et al.Composition dependence of oxide anion conduction in the BIMEVOX family[J].Solid State Ionics,1996,90:117-123.
  • 6Jacobsoone V,Follet H C,Boivin J C.Evidence of a new bismuth vanadium zinc oxyfluoride with the BIMEVOX structure[J].Solid State Ionics,1998,113-115:607-613.
  • 7Kurek P,Breiter M W.Thermal stability and ionic conductivity of the BIMEVOX.10 ceramics (ME = Zn,Ni)[J].Solid State Ionics,1996,86-88:131-135.
  • 8Bogusz W,Nelstrop J A G.Electrical and structural study of BICOVOX[J].Solid State Ionics,1996,86-88:261-266.
  • 9Abrahams I,Krok F,Nelstrop J A G.Defect Structure of quenched γ-BICOVOX by combined X-ray and neutron powder diffraction[J].Solid State Ionics,1996,90:57.
  • 10Cho H,Sakai G,Shimanoe K,et al.Behavior of oxygen concentration cells using BiCuVOx oxide-ion conductor[J].Sensors and Actuators B,2005,108:335-340.

同被引文献29

  • 1Achary S N, Mathews M D, Patwe S J, et al. High-temperature X-ray Diffraction and Dilatometric Studies on Some Oxygen ion Conducting Compounds[J]. J Mater Sci Lett, 1999,18(5):355-357.
  • 2Chadwick A V, Maltese C C, Morrison G, et al. Exafs Studies of the Cation Site in Bimevox Fast-ion Conductors[J]. Solid State Ionies, 1999,119 (1) : 79-84.
  • 3Pirovano C, Steil M C, Capoen E, et al. Impedance Study of the Electrical Properties of Bimevoxes[J]. Solid State Ionies, 2005,176(25): 2079-2083.
  • 4Abrahams I, Krok F, Nelstmp J A. Defect Structure of Quenched γ-Bicovox by Combined X-ray and Neutron Powder Diffraction[J]. Solid State Ionics, 1996,90 (1-4): 57-65.
  • 5Kurek P,Breiter M W. Thermal Stability and Ionic Conductivity of the Bimevox. 10 Ceramics (ME= Zn, Ni) [J]. Solid State Ionics, 1996, 86-88(1): 131-135.
  • 6Hemvoches C H, Stell M C, Muccillo R. Synthesis by the Polymeric Precursor Technique of Bi2Co0.1 V0.9O5.35 and Electrical Properties Dependence on the Crystallite Size[J]. Solid State Sciences,2004,6(2) :173-177.
  • 7Steil M C, Fouletier J, Kleitza M, et al. Bicovox; Sintering and Grain Size Dependence of the Electrical Properties[J]. J Eur Ceram Soc, 1999, 19(6-7): 815-818.
  • 8Zhang F, Xu K Q, Xu Q, et al. Synthesis, Sintering and Oxygen Ionic Conducting Properties of Bi2Cu0.1V0.9O5.35-δ[A]. Proceedings of the 10th Asian Conference on Solid State Ionics[C]. Kandy, Sri Lanka: Asian Society for Solid State Ionics, 2006. 236-243.
  • 9Abrahams I, Krok F, Malys M, et al. Phase Transition Studies in Bimevox Solid Electrolytes Using AC Impedance Spectroscopy[J]. Solid State Ionies, 2005,176(25-28) :2053-2058.
  • 10Akiteru W, Kaushik D. Time-dependent Degradation Due to the Gradual Phase Change in Bocuvox and Bicovox Oxide-ion Conductors at Temperatures Below About 500℃ [J]. Solid State Chem, 2002, 163(1):224-230.

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硅酸盐通报
2006年 第5期

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