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天然气水合物生成条件的测定和计算 被引量:8

Measurement and calculation of hydrate formation conditions for natural gases
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摘要 利用全透明蓝宝石水合物静力学实验装置,测定了4种塔里木油田天然气在纯水中的水合物生成条件.将Chen-Guo水合物模型应用于天然气水合物生成条件的计算,实验测定的4种天然气水合物生成条件的计算结果和实验结果符合得很好. Hydrate formation conditions of four natural gases in pure water were measured in a sapphire cell using the “pressure search” method. The experiment temperature range was 274.15 K-284.15 K, and the pressure was 1.04-7.05 MPa. The Chen-Guo hydrate model was used to calculate the hydrate formation conditions of these four natural gases. The average deviation of calculated values to experimental ones was only 0. 75%. Good agreement between experimental data and calculated values was achieved. The obtained experimental data are valuable for designing an industrial process to transporting natural gases.
出处 《化工学报》 EI CAS CSCD 北大核心 2006年第10期2416-2419,共4页 CIESC Journal
基金 国家自然科学基金项目(20490207 90210020).~~
关键词 气体水合物 天然气 模型 生成条件 gas hydrate natural gas model formation condition
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参考文献8

  • 1Sloan E,Dendy Jr.Clathrate Hydrate of Natural Gases.2nd ed.New York:Marcel Dekker,Inc,1997:11-12
  • 2Chen G J,Guo T M.Thermodynamic modeling of hydrate formation based on new concepts.Fluid Phase Equilibria,1996,122(1/2):43-65
  • 3Mei D H,Guo T M.Experimental and modeling studies on the hydrate formation of a methane+nitrogen gas mixture in the presence of aqueous electrolyte solutions.Ind.Eng.Chem.Res.,1996,35(11):4342-4347
  • 4Mei D H,Guo T M.Hydrate formation of a synthetic natural gas mixture in aqueous solutions containing electrolyte,methanol and(electrolyte+methanol).J.Chem.Eng.Data,1998,43(2):178-182
  • 5Fan S S,Guo T M.Hydrate formation of CO2 rich binary and quaternary gas mixtures in aqueous sodium chloride solutions.J.Chem.Eng.Data,1999,44(4):829-832
  • 6Zhang S X,Chen G J.Hydrate formation of hydrogen+hydrocarbon gas mixtures.J.Chem.Eng.Data,2000,45(5):908-911
  • 7张世喜,陈光进,杨兰英,马昌峰,郭天民.含氢气体水合物生成条件的测定和计算[J].化工学报,2003,54(1):24-28. 被引量:9
  • 8van der Waals J H,Platteeuw J C.Clathrate solutions.Adv.Chem.Phys.,1959,2(1):2-57

二级参考文献12

  • 1[1]Holder G D, Stephenson J L, Joyce J J, John V T, Kamath V A, Malekar S.Formation of Clathrate Hydrates in Hydrogen-rich Gases. Ind. Eng. Chem., 1983,22:170-171
  • 2[2]Ng H J, Robinson D B.The Measurement and Prediction of Hydrate Formation in Liquid Hydrocarbon-water Systems.Ind. Eng. Chem. Fundam.,1976,15(4):293-298
  • 3[3]Parrish W R, Prausnitz J M.Dissociation Pressure of Gas Hydrates Formed by Gas Mixtures. Ind. Eng. Chem. Process Des. Dev., 1972,11(1):26-35
  • 4[4]Adisasmito S, Frank R J, Sloan E D.Hydrates of Carbon Dioxide and Methane Mixtures. J.Chem. Eng. Data, 1991,36:68-71
  • 5[5]Thakore J L, Holder G D. Solid-Vapor Azeotropes in Hydrate Forming Systems.Ind. Eng. Chem. Res., 1987,26:462-469
  • 6[6]Yamanlar S, Poettmann F H, Sloan E D. Control Hydrate Formation.Hydrocarbon Processing, 1991, 70(9): 155-161
  • 7[7]Sloan E D Jr. Clathrate Hydrates of Natural Gases. New York: Marcel Dekker, Inc.,1990
  • 8[8]Prausnitz J M. Molecular Thermodynamics of Fluid Phase Equilibria. Englewood Cliffs, N J:John Wiley,1969.391
  • 9[9]Chen Guangjin(陈光进),Ma Qinglan(马庆兰),Guo Tianmin(郭天民).A New Mechanism for Hydrate Formation and a Simplified Hydrate Thermodynamic Model.Journal of Chemical Industry and Engineering(China)(化工学报), 2000,51(5):626-631
  • 10[10]Peng DY, Robinson DB.A New Tow-Constant Equation of State.Ind. Eng. Chem. Fundam., 1976,15(1):59-64

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