摘要
对热剪切循环条件下Sn-3.5Ag-0.5Cu/Cu和Sn-Pb/Cu界面上原子扩散和化合物的生长行为进行了研究。结果表明:再流焊后,在两界面上均形成一种Cu6Sn5化合物;随着热剪切循环周数的增加,两界面上化合物的形态均从扇贝状向层状生长,其厚度随循环周数的增加而增加,且生长基本遵循抛物线规律,说明Cu原子的扩散控制了Cu6Sn5化合物的生长。界面近域的钎料内,颗粒状的Ag3Sn聚集长大成块状。
The atoms diffusion and growth behavior of intermetallic compounds (IMCs) at Sn-Ag-Cu/Cu and Sn-Pb/Cu interfaces under the thermal-shearing cycling condition were investigated. The results show that Cu6 Sn5 forms at the two interfaces, and its thickness increases with the thermal-shearing cycling. The morphology of Cu6Sn5 varies from scallop-type to planar-type with increasing thermal-shearing cycling periods. The IMC growth follows growth kinetics of parabola, implying that IMC growth is controlled by Cu atom diffusion. In the solder, branch-like Ag3 Sn forms after reflowing, congregates to grow up to planar after thermal-shearing cycling.
出处
《中国有色金属学报》
EI
CAS
CSCD
北大核心
2006年第10期1705-1709,共5页
The Chinese Journal of Nonferrous Metals
基金
国家自然科学基金资助项目(50371010)