摘要
本文在强场图象下推导了3d4/3d6离子在三角晶场中包括自旋-轨道相互作用的哈密顿矩阵公式.采用双SO轨道模型计算了Fe2+离子在Ⅱ-Ⅵ半磁半导体CdTe和CdSe中的基态精细结构分裂(FSS).理论计算的FSS和实验结果符合很好.
In this paper, the Hamiltonian matrix of 3d 4/3d 6 ion in trigonal symmetry, including the crystal field and the spin orbit interactions, has been derived. The fine structure splittings(FSS) of the ground state of Fe 2+ ions in Ⅱ Ⅵ semimagnetic semiconductors (SMSC) CdTe and CdSe are obtained by a molecular orbital approach. The theoretical FSS are in good agreement with the experiments. The results obtained indicate that spin triplet contribution to FSS of the ground state is very important.
出处
《四川师范大学学报(自然科学版)》
CAS
CSCD
1996年第5期34-36,共3页
Journal of Sichuan Normal University(Natural Science)
基金
国家自然科学基金