过渡金属醋酸盐与邻菲咯啉的室温固相配位化学反应研究

The Solid State Reactions of Phenanthroline With M (Ac)_2·nH_2O(M=Co, Ni, Cu, Zn, n = 1, 2, 4) At Room Temperature

本文研究了Ｃ０（Ａｃ）２·４Ｈ２Ｏ，Ｎｉ（Ａｃ）２４Ｈ２Ｏ，Ｃｕ（Ａｃ）２·Ｈ２Ｏ，Ｚｎ（Ａｃ）２·２Ｈ２Ｏ与邻菲咯啉在室温（２０土２℃）条件下的固相配位化学反应，讨论了反应物分子结构对固相反应的影响，通过固相反应一步合成了相应的配合物，经元素分析、红外光谱，Ｘ－射线衍射测定，确定了固相合成产物的组成。

The solid state reactions of phenanthroline (Phen) with Co (Ac)2,·4H2O. Ni(Ac)2·4H2O,Cu(Ac )2·H2O and Zn (Ac )2·2H2O have been investigated at room telnpelature. Influences of molecular structures of these reactants on solid state reactions are discussed.The solid products are characterized by elemental analysis,IR and XRD.