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吖啶基功能化二苯并-18-冠-6的合成 被引量：2

Synthesis of Dibenzo-18-crown-6 Functioned by Acridinyl
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摘要 通过改变离去基团的活性、亲核试剂、溶剂的极性、离子性及反应温度等,对传统的U llm ann合成法进行了优化,将二苯并-18-冠-6进一步功能化,合成了未见文献报道的N,N′-二-(9-吖啶基)-4,4′-二氨基二苯并-18-冠-6,收率在87%以上。其结构经1H NMR,IR及元素分析表征。 The traditional Ullmann synthesis of C-N bond was optimized by changing polar and ionic properties of the solvent, activity of leaving group and reaction temperature. A new compound, N,N＇-di-9-acridinyl-4,4＇-diamino-dibenzo-18.crown-6, was synthesized and the structure was characterized by 1^H NMR, IR and elemental analysis. The yield was over 87%.
作者 严正权 聂丽 张强 周运友
机构地区 皖西学院化学与生命科学系 安徽师范大学
出处 《合成化学》 CAS CSCD 2006年第6期600-602,共3页 Chinese Journal of Synthetic Chemistry
基金 安徽省高校青年教师科研资助项目(2005jq1161)
关键词 吖啶 二苯并-18-冠-6 合成 acridine dibenzo-18-crown-6 synthesis
分类号 O621.3 [理学—有机化学] O626.32 [理学—有机化学]
  • 相关文献

参考文献9

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共引文献13

同被引文献14

  • 1严正权,刘传芳.二苯并-18-冠-6的合成条件的优化[J].安徽化工,2005,31(6):29-30. 被引量：6
  • 2严正权,张强,王家骅,聂丽.二苯并-18-冠-6的合成及其光谱性质[J].光谱实验室,2006,23(5):913-917. 被引量：2
  • 3C.J.Pedersen. Cyclic polyethers and their complexs with metal salts. J.Am.Chem.Soc, 1967,89 ( 26 ) :7017-7038.
  • 4T. Akutagawa,D. Endo, H. Imai, et al. Formation of p-Phenyl enediamine-Crown Ether- [PMo12O40]^4- Salts, Inorg. Chem., 2006, 45(21) : 8628-8637.
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引证文献2

合成化学
2006年 第6期

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