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α-大马酮香料合成方法的改进 被引量：2

The improvement synthesis of α-damascone
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摘要 采用原料价廉、易得,操作简便的合成路线,从柠檬醛出发,与烯丙基溴化镁发生格氏反应,再经氧化、异构化、环化,最后得到α-大马酮即甲位突厥酮,并对氧化等步骤进行了改进。 The synthesis method used was simple and the raw material was cheap and readily available. Citral was used as the starting material, which reacted with allyl magnesium bromide to yield an alcohol compound. The alcohol compound was oxidized, isomerized, and cyclized to give α-damascone.
作者 李卫明 王植材 陈浩林
机构地区 广东光华化学厂有限公司
出处 《化学试剂》 CAS CSCD 北大核心 2006年第11期699-700,共2页 Chemical Reagents
关键词 α-大马酮(甲位突厥酮) 合成 柠檬醛 α-damascone synthesis citral
分类号 O624.42 [理学—有机化学]
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参考文献7

  • 1COOKSON R,TUDDENHAM R M.Lewis-acid catalyzed diels-alder reaction with inverse electron demand.alternative synthesis of α-damascone[J].J.Chem.Soc.Commun.,1973,(19):742.
  • 2COOKSON R,TUDDENHAM R M.Synthesis of α-damascone[trans-1-(2,6,6-trimethylcyclohex-2-enyl)but-2-en-1-one] by a catalyzed diels-alder reaction with inverse electron demand[J].J.Chem.Soc.,Perkin Trans.1,1978,(16):678-680.
  • 3FEHR C,GALINDO J.Reaction of ester enolates with nucleophiles[J].J.Org.Chem.,1988,53(8):1 828-1 830.
  • 4NAKATANI Y.Nouvelle synthese de α-damascone[J].Agr.Biol.Chem.,1974,38(7):1 351-1 354.
  • 5KENJI M,PUAPUUNCHIYARAAN P,MASAMICHI I.Production of (s)-(-)-alpha-damascone and its new intermediate:JP,4 279 536[P].1992-10-05.
  • 6KAZUNORI W.Method of producing damascone or damascenone:JP,2 001 247 504[P].2001-09-11.
  • 7盖尔曼 H,勃拉特 A.有机合成(中译本)[M].第一集.科学出版社,1957:21-33.

同被引文献17

  • 1PATERSON A,PIGGOTT J R,JIANG J.Sensory-instrumental correlation strategies to study varietal characters in raspberry flavour[J].Food Qual.Prefer.,1993,4(1/2):85-86.
  • 2SUZUKI M,MATSUMOTO S,MIZOGUCHI M,et al.Identification of (3S,9R)-and (3S,9S)-megastigma-6,7-dien-3,5,9-triol 9-O-beta-D-glucopyranosides as damascenone progenitors in the flowers of Rosa damascena Mill[J].Biosci.,Biotechnol.,Biochem.,2002,66(12):2 692-2 697.
  • 3CHEVANCE F,GUYOT-DECLERCK C,DUPONT J,et al.Investigation of the beta-damascenone level in fresh and aged commercial beers[J].J.Agric.Food Chem.,2002,50(13):3 818-3 821.
  • 4LAPCZYNSKI A,LALKO J,MCGINTY D,et al.Fragrance material review on damascenone[J].Food Chem.Toxicol.,2007,45(1):172-178.
  • 5DANIEL M A,PUGLISI C J,CAPONE D L,et al.Rationalizing the formation of damascenone:synthesis and hydrolysis of damascenone precursors and their analogues,in both aglycone and glycoconjugate forms[J].J.Agric.Food Chem.,2008,56(19):9 183-9 189.
  • 6COOKSON R C,TUDDENHAM R M.A Lewis acid catalysed Diels-Alder reaction with inverse electron demand;an alternative synthesis of α-damascone[J].J.Chem.Soc.,Chem.Commun.,1973,(19):742.
  • 7COOKSON R C,TUDDENHAM R M.Synthesis of α-damascone[trans-1-(2,6,6-trimethylcyclohex-2-enyl)but-2-en-1-one]by a catalysed Diels-Alder reaction with inverse electron demand[J].J.Chem.Soc.,Perkin Trans.1,1978,(6):678-680.
  • 8FEHR C,GALINDO J.Reaction of ester enolates with nucleophiles.stereocontrolled formation of ketone and aldehyde enolates[J].J.Org.Chem.,1988,53(8):1 828-1 830.
  • 9KAZUNORI W.Method of producing damascone or damascenone:JP,2 001 247 504[P].2001-09-11.
  • 10JANITSCHKE L,HOFFMANN W.Preparation of compounds of the 4-oxodamascone series,and novel scents from this class of compounds:US,4 550 211[P].1985-10-29.

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化学试剂
2006年 第11期

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