金属-有机络合聚合物(MOCPs)的研究进展

Progress in porous metal-organic coordination polymers

从配体的角度对中心离子与多齿配体间形成的稳定多孔金属-有机络合聚合物(MOCPs)的发展现状进行了综述。指出该材料自成为研究热点以来,各研究小组在对不同的构件分子进行组合构建新的MOCPs方面富有成效的工作,极大地丰富了络合聚合物的结构数据,但这种材料最引人注目的特性——孔及表面性质的可调控性及其对其各种应用特性,如分子识别、择形催化、择形吸附等所能带来的影响方面的研究还很不够。

The current progress in porous metal-organic coordination polymers （MOCPs） built by the chelate bonds between center metal ions and ligands is reviewed according to the ligand types in this paper. It is pointed out that a lot of structure data have been accumulated by many research groups through their efficient jobs in the MOCPs synthesis since the materials became a hotspot in 1990s, but there is some shortage in the research of the relationship between the regulable superiority in pore structure and their applied properties, like molecular identification, shape-selecting adsorption or catalysis, etc. And the structure-effect relations are just the most remarkable of the materials.