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苯基三羰基合锰(I)配合物的光化学反应

Photochemical Reaction of(Benzene) Manganese(I) Tricarbonyl Complex
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摘要 首次利用光照的手段实现了苯基三羰基合锰(I)配合物的去配位作用,得到了芳香化合物———苯.产率高达90%以上,反应的量子产率高达0.5. Irradiation of (benzene)manganese(Ⅰ) tricarbonyl complex results in benzene formation with yield of 90 % and quantum yield of 0.5, respectively.
出处 《感光科学与光化学》 CSCD 2006年第6期401-403,共3页 Photographic Science and Photochemistry
基金 科技部国家重点基础研究发展规划项目(2003CB716802 2004CB719903) 国家自然科学基金资助项目(20125207 20333080 20332040 20672122) 中科院基础局资助项目(KJCX2-SW-H15).
关键词 苯基三羰基合锰(Ⅰ)配合物 光化学反应 去配位作用 (benzene) manganese (Ⅰ) tricarbonyl complex photochemical reaction decomplexation
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参考文献10

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