摘要
Reaction of the β-diketiminate ytterbium dichloride LYbCl2(THF)2(L=2,6-Pri2C6H3)NC(Me)CHC(Me)N(C6H3-2,60Pri2)(1)with 2equiv off C5H5Na in THF gave rise to the title complex LYb(C5H5)2(2),and the crystal structure of the complex 2 was determined by single-crystal X-ray diffraction.The crystal belongs to orthorhombic,space group P21212 with a=4.3219(6),b=1.6602(2),c=0.9604(1)nm,V=6.891(2)nm3,Z=8,Dc=1.390 Mg·m-3,R=0.0331,wR=0.0535.In the molecular structure of the title complex,the central metal atom Yb is coordinated by two cyclopentadienyl rings and two nitrogen atomes of β-diketiminate group to form an eight-coordinate distorted tetrahedral geometry.
Reaction of the β - diketiminate ytterbium dichloride LYbCl2(THF)2(L = 2,6 - Pr2^iC6H3)NC(Me)CHC(Me)N(C6H3-2,60Pr2^i)(1)with 2equiv off C5H5Na in THF gave rise to the title complex LYb(C5H5)2(2), and the crystal structure of the complex 2 was determined by single - crystal X - ray diffraction. The crystal belongs to orthorhombic, space group P21212 with a = 4.3219(6), b = 1.6602(2), c = 0.9604(1)nm, V = 6.891(2)nm^3, Z = 8, Dc = 1.390 Mg·m^-3, R = 0.0331, wR = 0.0535. In the molecular structure of the title complex, the central metal atom Yb is coordinated by two cyclopentadienyl rings and two nitrogen atomes of β - diketiminate group to form an eight - coordinate distorted tetrahedral geometry.
出处
《化学研究与应用》
CAS
CSCD
北大核心
2006年第11期1336-1339,共4页
Chemical Research and Application
基金
国家自然科学基金资助项目(20472063)