摘要
基于普遍化范德华配分函数理论,应用由局部组成概念导出的方阱流体配位数模型导出了链状分子混合物的配位数模型,并由此建立了一个新的活度系数模型;将其应用于高度非理想体系汽-液平衡活度系数的关联,结果与Wilson方程相当,但方程参数随温度变化较小;其于Newton-Raphson-Gauss液-液平衡算法,应用新模型对烃-水体系的液-液平衡进行了关联计算。
A new activity coefficient model was established based on the generalized van der Waals partition function and the coordination number model for mixtures with chainlike molecules.When applied to correlate the VLE data of highly nonideal systems,comparable results were obtained with wilson model.but the parameter values are less sensitive to temperature.In addition,the new activity coefficient model is also applicable to liquid liquid equilibrium(LLE) system,the test results on the LLE calculation for hydrocarbon water systems indicate that better results were obtained as compared with NRTL model.
出处
《化学工程》
EI
CAS
CSCD
北大核心
1996年第6期59-63,共5页
Chemical Engineering(China)
基金
国家自然科学基金
关键词
配位数
活度系数模型
烃
水体系
液液平衡
coordination number,chainlike molecules,activity coefficient model,hydrocarbon water systems,liquid liquid equilibrium