摘要
A novel 12-ring network coordination polymer, { [ Cu （ C4 N2 H10 ） 4 ]2 H4 V4 O14 } n （ denoted as QUST-4）, was hydrothermally synthesized and structurally determined by X-ray single-crystal diffraction analysis. QUST-4 was crystallized in a monoelinic system with space group P21/n. The parameters of the unit cell are a = 1. 0497（2） nm, b = 1.6728（3） nm, c=1.2857（3） nm, 3=94. 14（3）°, V=2.2517（8） nm^3, Z=4, Dcal = 1.841 Mg/m^3, R1 = 0. 1071, and wR3 =0. 2703. The largest difference peak and hole were 2284 and - 1040 c/nm^3, respectively. The SBU（ secondary building unit） of QUST-4 was a new cyclo- aggregate of polyoxovanadate cyelo-[ S4V4O14 ]^4 - , different from cyclo-[ V4O12 ]^4-, which was condensed from two tetrahedral and two trigonal bipyramids via ahernate arrangement. Cu（piper） 4 （ piper = piperazine ） group connected the cyclo- [ H4 V4 O14 ] ^4 - anions to form the 12-ring network. The adjacent layers were linked by van der Walls forces.
A novel 12-ring network coordination polymer, { [ Cu （ C4 N2 H10 ） 4 ]2 H4 V4 O14 } n （ denoted as QUST-4）, was hydrothermally synthesized and structurally determined by X-ray single-crystal diffraction analysis. QUST-4 was crystallized in a monoelinic system with space group P21/n. The parameters of the unit cell are a = 1. 0497（2） nm, b = 1.6728（3） nm, c=1.2857（3） nm, 3=94. 14（3）°, V=2.2517（8） nm^3, Z=4, Dcal = 1.841 Mg/m^3, R1 = 0. 1071, and wR3 =0. 2703. The largest difference peak and hole were 2284 and - 1040 c/nm^3, respectively. The SBU（ secondary building unit） of QUST-4 was a new cyclo- aggregate of polyoxovanadate cyelo-[ S4V4O14 ]^4 - , different from cyclo-[ V4O12 ]^4-, which was condensed from two tetrahedral and two trigonal bipyramids via ahernate arrangement. Cu（piper） 4 （ piper = piperazine ） group connected the cyclo- [ H4 V4 O14 ] ^4 - anions to form the 12-ring network. The adjacent layers were linked by van der Walls forces.
基金
Supported by the Scientific Research Foundation for the Returned Overseas Chinese Scholars, the Ministry of Education, Chinaand the Doctoral Fund of Qingdao University of Science &Technology.
