过渡金属不对称催化氧杂苯并降冰片烯开环反应的研究进展

Progress in Transition Metal-Catalyzed Asymmetric Ring Opening Reactions of Oxabenzonorbornadienes

综述了近年来过渡金属不对称催化氧杂苯并降冰片烯开环反应的研究进展,包括钯催化、镍催化、铜催化和铑催化四部分内容,并对部分反应的机理进行了介绍.

The recent progress in transition metal-catalyzed asymmetric ring opening （ARO） reactions of oxabenzonorbornadienes including the Pd-, Ni-, Cu- and Rh-catalyzed ARO is reviewed. Moreover, the catalytic possible mechanisms are discussed.