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稀土系储氢合金性能影响因素的研究现状 被引量:5

Recent Research on Influence Factors of Capability of Rare -Earth-Based Hydrogen Storage Alloys
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摘要 稀土系AB5型储氢合金具有原料价格低、低温性能好以及高倍率性能优良等优点,目前被广泛用于Ni-MH电池负极材料。本文对稀土系储氢合金性能的影响因素:组成、制备方法、温度以及其他等因素的研究现状进行了综述。指出稀土系储氢合金目前存在的最大问题是放电性能低。 Rare-earth-based ABs-type hydrogen storage alloys are widely used as cathode materials of MH-Ni batteries for their advantages, such as, lower price of raw material, good properties in low temperature and excellent high-rate discharge capacity. Recent research development on influence factors of discharge capacity of rare-earth-based hydrogen storage alloys, including composition, preparing methods, work temperature and other methods, was reviewed. Currently, the main problem existing in low discharge capability of rare-earth -based hydrogen storage alloy is mentioned.
出处 《金属功能材料》 CAS 2006年第6期32-36,共5页 Metallic Functional Materials
基金 高等学校博士学科重点专项科研基金(资助号:20040008015)
关键词 NI-MH电池 储氢合金 研究现状 hydrogen storage alloys influence factors discharge capability
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参考文献29

  • 1Kuochih Hong,The development of hydrogen storage alloys and the progress of nickel hydride batteries[J].J Alloys and Comp,2001,321:307.
  • 2Guo J H,Jiang Z J,et al.Influence of Ce and Nd contents of Ml (NiCoMnAl)5 alloy on the performances of Ni-NH batteries[J].J Alloys and Comp,1999,293-295:821.
  • 3Ye H,Zhang H.et al,Effect of Ni content on the structure,thermodynamic and electrochemical properties of the non-stoichiometric hydrogen storage alloys[J].J of Alloys and Comp,2000,308:163.
  • 4Li Rong,Wu Jianmin,et al.Effects of rare-earth content and annealing on the electrochemical properties of Mm (NiCoMnAl) 5 hydrogen storage alloys[J].J of Alloys Comp,2004,363:292.
  • 5Liaoa B,Leia Y Q,et al.Effort of Co substituti-on for Ni on the structural and electrochemical properties of La2 Mg(Ni1-xCox)9 (x =0.1-0.5) hydrogen storage electrode all-oys[J].Electrochemica Acta,2004,50:1057.
  • 6Liu Yongfeng,Pan Hongge,Gao Mingxia.Investigation on the characteristics of La0.7 Mg0.3 Ni2.65 Mn0.1 Co0.75 + x (x = 0.00 -0.85)metal hydride electrode alloys for Ni/MH batteries Part[J].Phase structures and hydrogen storage,J of Alloys and Comp,2005,387:147.
  • 7Chiaki Iwakura,Takafumi Oura,et al.Efforts of alloy composition on hydrogen diffusion in the AB5-type hydrogen storage alloys[J].Electroanalytical Chemistry,1995,398:37
  • 8余学斌,陈金舟,吴铸,夏保佳.Cr含量对TiMn_(1.2-x)Cr_xV_(0.25)Fe_(0.05)合金吸/放氢性能的影响[J].金属学报,2004,40(5):527-530. 被引量:9
  • 9Ye Hui,Xia Baojia,et al.Effect of rare earth composition on the high-rate capability and low-temperature capacity of AB5-type hydrogen storage alloys[J].Power Sources,2002,111:145.
  • 10原鲜霞,马紫峰,刘汉三,徐乃欣.稀土组成对贮氢合金La_(0.8(1-x))Ce_(0.8x)(PrNd)_(0.2)B_5性能的影响[J].稀有金属材料与工程,2004,33(7):696-700. 被引量:13

二级参考文献63

  • 1张玉芬,侯勇,王健,宏存茂.MmB_5贮氢合金的结构和性能[J].物理化学学报,1994,10(7):644-647. 被引量:7
  • 2大角泰章.金属氢化物的性质与应用[M].北京:化学工业出版社,1990.6.
  • 3Liu K Y, Zhang P M, Tang Y G. Preparation of low cobalt high rate discharge hydrogen storage alloy MlNi3.85Co0.45Mn0.4Al0.3X0.1 (X= Mg, Si, Sn) [J]. Transactions of Nonferrous Metals Society of China (English Edition), 2003, 13(2) .245~248.
  • 4Lichenberg F, Kohler U, Foler A, et al. Development of AB5 type hydrogen storage alloys with low Co content for rechargeable NiMH batteries with respect to electric vehicle applications[J]. Alloys and Comp. , 1997, 253~254:570~573
  • 5Zhou Y, Zhang Y F, Lei Y Q, et al. Activation of hydrogen storage electrode alloy Ml(NiCoMnTi) 5 produced by gas atomization [J]. Int J Hydrogen Energy, 1998, 23 (3):183-189
  • 6Munehisa I, Katsunori K, Satoshi K, et al. Effect of alkali - treatment of hydrogen storage alloy on the degradation of Ni/MH batteries[J]. J. Alloys and Comp. , 1999, 284:92-98
  • 7Imoto T, Kato K. Microstructure and electrochemical characteristics of surface - treated Mm (NiCoMnAl) 4.76 alloys for nickelmetal hydride batteries[ J ]. J Alloys and Comp. , 1999, 285: 272:278
  • 8Lei Y Q, Zhou Y, Luo Y C, et al. Preparation and electrochemical properties of unidirectionally solidified Ml ( NiCoMnTi ) 5 alloys[ J ]. J Alloys and Comp. 1997, 253 - 254:590-593
  • 9Wang C S,Electrochim Acta,1998年,43卷,3193页
  • 10Wang C S,J Electriochem Soc,1998年,145卷,1801页

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