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甲基叔戊基醚合成反应的热力学分析 被引量:1

THERMODYNAMIC ANALYSIS OF SYNTHESIS REACTION OF TERT-AMYL METHYL ETHER (TAME)
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摘要 利用戊烯与甲醇合成甲基叔戊基醚(TAME)反应的热力学平衡实验数据,选择不同的混合活度模型,分别计算得到了该反应体系的平衡常数,并与理论计算得到的平衡常数相比较,筛选出了适合该反应体系的活度计算模型。 Based on the thermodynamic equilibrium data of synthesis reaction of isoamylene and methanol to form tert-amyl methyl ether (TAME), the equilibrium constants of the reaction system are calculated with different mixing activity models and compared with those worked out by theoretical calculation. The appropriate activity model for this synthesis reaction system is selected.
出处 《炼油技术与工程》 CAS 北大核心 2006年第12期23-28,共6页 Petroleum Refinery Engineering
基金 中国石油中青年创新基金项目(05E7002)。
关键词 甲基叔戊基醚 戊烯 甲醇 合成反应 活度系数 平衡常数 热力学分析 TAME, amylene, methanol, synthesis reaction, activity coefficient, equilibrium constant,thermodynamic analysis
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参考文献10

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同被引文献10

  • 1刘立新,江洪波,刘明辉,翁惠新.裂解碳五合成甲基叔戊基醚体系的热力学特征[J].石油化工,2006,35(7):624-628. 被引量:15
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  • 5Manuela V F, Jose M L. Number of Actives Sites in TAME Synthesis: Mechanism and Kinetic Modeling. Ind Eng Chem Res, 2004, 43(17) :5 156 -5 165
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  • 7姚文生,陆贵根,张广平,方伯言,付力,杨智生.合成TAME宏观动力学的研究[J].石油化工,1998,27(6):391-395. 被引量:15
  • 8胡竞民,徐宏芬,鲁耘,李普阳,赵麒全,李雪.碳五馏份醚化多功能催化剂的研究[J].石油化工,1999,28(6):354-358. 被引量:7
  • 9孙恩顺.利用C_5馏分生产TAME的现状及展望[J].化工科技,1999,7(3):13-17. 被引量:10
  • 10王伟,郝兴仁,吕爱梅.TAME合成工艺技术[J].石油化工,2003,32(1):52-55. 被引量:14

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