摘要
本文合成了一个多功能臂大环多胺La(Ⅲ)配合物,通过光谱法研究了pH值、温度以及表面活性剂对α-吡啶甲酸对硝基苯酚酯(PNPP)催化水解反应的影响。结果表明非离子表面活性剂Brij35胶束体系的催化活性比阳离子表面活性剂CTAB胶束体系高。前者加速催化,后者则禁阻催化。
A macrocyclic polyarnines La( Ⅲ )-complex bearing multi-functional pendent has been synthesized in this paper. The effects of pH, reaction temperature, and nature of surfactants on the hydrolysis of PNPP have been investigated. The results indicated that the different micellar systems have the different catalytic activities, and the nonionic surfactant Brij35 has a higher effect than the cationic surfactant CTAB The former accelerated the speed of hydrolysis,the later inhibited the hydrolysis of PNPP.
出处
《化学研究与应用》
CAS
CSCD
北大核心
2006年第12期1389-1392,共4页
Chemical Research and Application
基金
四川省科技厅应用基础项目(04JY029-018)资助
四川省教育厅重点项目(2003A157)资助