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Heck Arylation of Cyclohexene Promoted by Ultrasonic and Microwave in Ionic Liquid: a Novel Method of the Synthesis of 3-Naphthylcyclohexene 被引量:1

Heck Arylation of Cyclohexene Promoted by Ultrasonic and Microwave in Ionic Liquid: a Novel Method of the Synthesis of 3-Naphthylcyclohexene
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摘要 Synthesis of 3-naphthylcyclohexene by the Heck reactions of bromonaphthalene and naphthyl triflates with cyclohexene catalyzed by palladiun and nickel complex (promoted by ultrasonic and microwave in ionic liquid of [bmim][BF4I) were performed with high yield and good regioselectivity. This method has advantages of environmentally benign, generality, simplicity and potential for recycling of ionic liquid and catalyat. Synthesis of 3-naphthylcyclohexene by the Heck reactions of bromonaphthalene and naphthyl triflates with cyclohexene catalyzed by palladiun and nickel complex (promoted by ultrasonic and microwave in ionic liquid of [bmim][BF4I) were performed with high yield and good regioselectivity. This method has advantages of environmentally benign, generality, simplicity and potential for recycling of ionic liquid and catalyat.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2006年第12期1534-1536,共3页 中国化学快报(英文版)
关键词 Naphthylcyclohexene palladium and nickel complex ionic liquid Heck reaction synthesis. Naphthylcyclohexene, palladium and nickel complex, ionic liquid, Heck reaction, synthesis.
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  • 1W. Pei,L. Sun,C. H. Xiong,C. Shen.16[].Chin Chem Lett.2005
  • 2M. Larhed,A. Hallberg.Handbook of Organopalladium Chemistry for Organic Synthesis[]..2002
  • 3I. P. Beletskaya,A. V. Cheprakov. Chem. Rev . 2000
  • 4W. Pei,J. Mo,J. Xiao. J. Orgnometall. Chem . 2005

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