β－氨基－α－羟乙基二茂铁及其过渡金属配合物的合成与表征

Synthesis and Characterization of β-Amino-α-Hydroxyethylferrrocene and Its Complexes of Transition Metals

用β－氨基－α－羟已基二茂铁与二价钴、镍、铜、锌、镉和汞的氯化物及醋酸铜在乙醇－水中反应，合成了七种新的配合物．探索出了适宜的反应条件，经元素分析，确定了新配合物的组成为：Ｌ２ＭＸ２·ｎＨ２Ｏ（Ｌ＝Ｆｃ─ＣＨＣＨ２ＮＨ２；Ｍ＝Ｃｏ２＋、Ｎｉ２＋、Ｃｕ２＋、Ｚｎ２＋、Ｃｄ２＋、Ｈｇ２＋，ｘ＝Ｃｌ－，ＣＨ３ＣＯＯ－；ｎ＝０，２，４）．通过红外光谱和核磁共振氢谱．对这些配合物的结构进行了表征．

Seven new complexes have been synthesized by the reaction of β-amino-α-hydrox-yethylferrocene with MCl2 or MAc2 (M=Co2+、Ni2+、Cu2+、Zn2+、Cd2+、Hg2+)in ethanol-water.They are stable in air. The compositon of these complexes have been confirmed by elemental analysis and their structures have been characterized by IR and HNMR spectra.